• CSCD中国科学引文数据库来源期刊
  • 中文核心期刊
  • 中国机械工程学会材料分会会刊
  • 中国科技核心期刊
高级检索

烧结温度对电磁压制Ag-25.5Cu-27Sn钎料显微组织及性能的影响

朱超勇, 黄尚宇, 周梦成, 颜士伟, 雷雨

朱超勇, 黄尚宇, 周梦成, 颜士伟, 雷雨. 烧结温度对电磁压制Ag-25.5Cu-27Sn钎料显微组织及性能的影响[J]. 机械工程材料, 2017, 41(12): 75-79. DOI: 10.11973/jxgccl201712016
引用本文: 朱超勇, 黄尚宇, 周梦成, 颜士伟, 雷雨. 烧结温度对电磁压制Ag-25.5Cu-27Sn钎料显微组织及性能的影响[J]. 机械工程材料, 2017, 41(12): 75-79. DOI: 10.11973/jxgccl201712016
ZHU Chaoyong, HUANG Shangyu, ZHOU Mengcheng, YAN Shiwei, LEI Yu. Effects of Sintering Temperature on Microstructure and Properties of Ag-25.5Cu-27Sn Brazing Filler Metal by Magnetic Pulse Compaction[J]. Materials and Mechanical Engineering, 2017, 41(12): 75-79. DOI: 10.11973/jxgccl201712016
Citation: ZHU Chaoyong, HUANG Shangyu, ZHOU Mengcheng, YAN Shiwei, LEI Yu. Effects of Sintering Temperature on Microstructure and Properties of Ag-25.5Cu-27Sn Brazing Filler Metal by Magnetic Pulse Compaction[J]. Materials and Mechanical Engineering, 2017, 41(12): 75-79. DOI: 10.11973/jxgccl201712016

烧结温度对电磁压制Ag-25.5Cu-27Sn钎料显微组织及性能的影响

基金项目: 

国家自然科学基金资助项目(51475345);华中科技大学材料成形与模具技术国家重点实验室开放基金资助项目(P2015-01)

详细信息
    作者简介:

    朱超勇(1991-),男,河南新乡人,硕士研究生

  • 中图分类号: TG425.2

Effects of Sintering Temperature on Microstructure and Properties of Ag-25.5Cu-27Sn Brazing Filler Metal by Magnetic Pulse Compaction

  • 摘要: 以纯金属粉末为原料,利用电磁压制技术制备了Ag-25.5Cu-27Sn钎料,并在100~500℃保温30 min进行烧结,研究了烧结温度对钎料相对密度、物相组成、显微组织、熔化特性,以及对其钎焊铜接头微观形貌和抗拉强度的影响。结果表明:随烧结温度的升高,钎料的相对密度先降低后升高,400℃烧结钎料的相对密度高于未烧结钎料的,并生成了稳定的ε1-Cu3Sn和ε2-Ag3Sn相;烧结使钎料的熔化温度略有提高,400℃烧结钎料的熔化温度比250℃烧结的降低了约4℃;400℃烧结钎料钎焊铜接头焊缝中的气孔数明显较少、组织均匀细小,其抗拉强度比未烧结钎料钎焊铜接头的提高了16%。
    Abstract: Ag-25.5Cu-27Sn brazing filler metal was prepared by magnetic pulse compaction using pure metal powders as raw materials, and sintered at 100-500℃ for 30 min. The effects of sintering temperature on relative density, phase composition, microstructure, melting property of the brazing filler metal, and on the micromorphology and tensile strength of the brazed Cu joint were studied. The results show that the relative density of the brazing filler metal first decreased then increased with the increase of sintering temperature. The relative density of the brazing filler metal sintered at 400℃ was higher than that of the unsintered brazing filler metal, and the stable phases of ε1-Cu3Sn and ε2-Ag3Sn were formed. The melting temperature of the brazing filler metal was improved by sintering, and that of the brazing filler metal sintered at 400℃ was about 4℃ lower than that sintered at 250℃. With 400℃ sintered brazing filler metal, the number of pores in weld of the brazed Cu joint was relatively small and the microstructure was relatively homogeneity and fine. The tensile strength was 16% higher than that of Cu joint brazed with the unsintered filler metal.
  • [1] 张启运,庄鸿寿. 钎焊手册[M]. 2版. 北京:机械工业出版社, 2008.
    [2] 陈登权,李伟,罗锡明,等. 电子工业用金基和银基中温钎料的研究进展[J]. 贵金属,2009(3):62-67.
    [3] 甘卫平,陈慧,杨伏良. Ag-Cu-In-Sn钎料加工工艺的研究[J]. 材料导报,2007(3):156-158.
    [4]

    MA X, LI L, ZHANG Z, et al. Effects of rare earth La on microstructure and properties of Ag-21Cu-25Sn alloy ribbon prepared by melt spinning[J]. Materials & Design, 2015, 83:1-5.

    [5] 徐锦锋,张晓存, 翟秋亚,等. 镍对Ag-Cu-Sn-In钎料组织及加工性能的影响[J]. 焊接学报, 2011, 32(11):65-68.
    [6] 李良锋,丘泰,李晓云,等. 机械合金化法制备57.6Ag-22.4Cu-10.5In-9.5Sn合金粉末及其性能[J]. 机械工程材料,2008,32(8):30-32.
    [7] 史耀武,雷永平, 夏志东,等. 无铅焊膏的设计与展望[J]. 电子元件与材料, 2008, 27(9):31-34.
    [8] 黄尚宇,施健, 孟正华,等. PZT陶瓷粉末低电压电磁压制实验研究[J]. 塑性工程学报, 2007, 8(1):42-47.
    [9]

    ZHOLNIN A, KOVALEVA I, MEDVEDEV P, et al. Difference of magnetic pulse compaction from traditional uniaxial pressing of alumina nanopowders[J]. Physics Procedia, 2015, 72:382-385.

    [10] 徐志坤. 无镉中温银基钎料的低电压电磁压制及烧结工艺研究[D].武汉:武汉理工大学,2012.
    [11] 张志力,熊惟皓,张国鹏.烧结温度对(Ti,W,Mo)C-Ni金属陶瓷组织与性能的影响[J].机械工程材料,2013,37(12):46-49.
    [12] 蔺绍江,熊惟皓,姚振华,等. 烧结温度对316不锈钢粉末冶金烧结体组织和性能的影响[J]. 机械工程材料,2011, 35(1):22-25.
    [13] 汤文明, IVEY G D. 电沉积Ag/Sn偶界面反应及其动力学[J]. 中国有色金属学报, 2009, 19(5):930-935.
    [14] 宋玉强, 李世春. Cu粉和Sn粉相界面扩散溶解层的研究[J]. 稀有金属材料与工程, 2007, 36(增刊3):217-221.
    [15]

    YEN Y, CHEN S. Phase equilibria of the Ag-Sn-Cu ternary system[J]. Journal of Materials Research, 2004, 19(8):2298-2305.

计量
  • 文章访问数:  0
  • HTML全文浏览量:  0
  • PDF下载量:  0
  • 被引次数: 0
出版历程
  • 收稿日期:  2016-12-12
  • 修回日期:  2017-09-19
  • 刊出日期:  2017-12-19

目录

    /

    返回文章
    返回