Abstract:
Binary system samples and Ta
2O
5-WO
3-RO
2 (R=Zr,Ti) ternary system samples were prepared after holding at 1 200℃ for 18 h with Ta
2O
5, WO
3, ZrO
2 and TiO
2 as raw materials. The phase composition was analyzed and the subsolidus phase diagrams of the Ta
2O
5-WO
3-RO
2 ternary systems at 1 200℃ were obtained according to the interaction and coexistence of each phase. The results show that five compounds of Ta
22W
4O
67, Ta
2WO
8, Ta
16W
18O
94, TiTa
2O
7 and TaZr
2.75O
8 were produced when the binary systems composed of Ta
2O
5, WO
3, ZrO
2 and TiO
2 were heated at 1 200℃ for 18 h. Four Coexisting triangles of Ta
16W
18O
94-WO
3-TiO
2, Ta
2WO
8-Ta
16W
18O
94-TiO
2, Ta
2WO
8-TiTa
2O
7-TiO
2 and Ta
2WO
8-TiTa
2O
7-Ta
22W
4O
67 and a solid solution region of Ta
2O
5, WO
3 and TiO
2 existed in the Ta
2O
5-WO
3-TiO
2 ternary subsolid system. Four coexistence triangles of Ta
2WO
8-Ta
22W
4O
67-TaZr
2.75O
8, Ta
2WO
8-Ta
16W
18O
94-TaZr
2.75O
8, WO
3-Ta
16W
18O
94-TaZr
2.75O
8 and WO
3-ZrO
2-TaZr
2.75O
8 and a solid solution region of Ta
2O
5, WO
3 and ZrO
2 existed in the Ta
2O
5-WO
3-ZrO
2 ternary subsolid system.