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    王温栋, 刘强, 张力文, 吕祥鸿, 赵国仙, 李丹平. 不同温度火烧驱油工况下油套管用钢的腐蚀行为[J]. 机械工程材料, 2018, 42(11): 11-16. DOI: 10.11973/jxgccl201811003
    引用本文: 王温栋, 刘强, 张力文, 吕祥鸿, 赵国仙, 李丹平. 不同温度火烧驱油工况下油套管用钢的腐蚀行为[J]. 机械工程材料, 2018, 42(11): 11-16. DOI: 10.11973/jxgccl201811003
    WANG Wendong, LIU Qiang, ZHANG Liwen, LÜ Xianghong, ZHAO Guoxian, LI Danping. Corrosion Behavior of Oil Casing Steel under Combustion Drive Oil Condition at Different Temperatures[J]. Materials and Mechanical Engineering, 2018, 42(11): 11-16. DOI: 10.11973/jxgccl201811003
    Citation: WANG Wendong, LIU Qiang, ZHANG Liwen, LÜ Xianghong, ZHAO Guoxian, LI Danping. Corrosion Behavior of Oil Casing Steel under Combustion Drive Oil Condition at Different Temperatures[J]. Materials and Mechanical Engineering, 2018, 42(11): 11-16. DOI: 10.11973/jxgccl201811003

    不同温度火烧驱油工况下油套管用钢的腐蚀行为

    Corrosion Behavior of Oil Casing Steel under Combustion Drive Oil Condition at Different Temperatures

    • 摘要: 通过模拟火烧驱油工况,研究了油套管用N80钢、BG80-3Cr钢、P110钢、BG90H钢、BG90H-9Cr钢和BG90H-13Cr钢在不同温度下的腐蚀行为,分析了其腐蚀机制。结果表明:在较低温度(50℃)下,试验钢主要发生CO2和氧腐蚀,腐蚀产物为FeCO3,腐蚀产物膜的保护性较差,均匀腐蚀速率较高;在较高(150℃)温度下,氧腐蚀占主导作用,腐蚀产物为Fe3O4和FeCO3,腐蚀产物膜的保护性下降,均匀腐蚀速率增大;在高温(250℃)条件下,腐蚀机制为氧腐蚀,腐蚀产物为Fe3O4,Fe3O4水化物膜的保护性较强,均匀腐蚀速率降低;N80钢、BG80-3Cr钢、P110钢、BG90H钢的均匀腐蚀速率均明显高于BG90H-9Cr钢和BG90H-13Cr钢的,且在50,150℃时的均高于0.2 mm·a-1;BG90H-9Cr钢和BG90H-13Cr钢在试验条件下的均匀腐蚀速率都低于0.2 mm·a-1,在火烧驱油工况下具有良好的耐均匀腐蚀性能。

       

      Abstract: The corrosion behavior of oil casing steels N80, BG80-3Cr, P110, BG90H, BG90H-9Cr and BG90H-13Cr at different temperatures was investigated under simulated combustion drive oil condition, and the corrosion mechanism was analyzed. The results show that at a relatively low temperature (50℃), oxygen and CO2 corrosion mainly occurred in the tested steels. The corrosion product was FeCO3 and had poor protection poerformance. Therefore the average corrosion rate was relatively high. At a relatively high temperature (150℃), oxygen corrosion gradually took the dominant role. The corrosion products consisted of Fe3O4 and FeCO3, whose protection performance decreased, and the average corrosion rate increased. At a high temperature (250℃), the corrosion mechanism was oxygen corrosion. The corrosion product was Fe3O4. The Fe3O4 hydrate film had high protection performance, and uniform corrosion rate decreased. The average corrosion rates of N80 steel, BG80-3Cr steel, P110 steel, BG90H steel were significantly higher than those of BG90H-9Cr steel and BG90H-13Cr steel, and were all higher than 0.2 mm·a-1 at 50,150℃. The average corrosion rates of BG90H-9Cr steel and BG90H-13Cr steel were both lower than 0.2 mm·a-1, indicating good corrosion resistance under combustion drive oil condition.

       

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