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    敏化态430不锈钢在食物模拟溶液中的耐腐蚀性能

    Corrosion Resistance of Sensitized 430 Stainless Steel in Food Simulation Solution

    • 摘要: 430不锈钢试样在进行不同程度的敏化后,在5%(质量分数,下同)NaCl溶液、4%(体积分数,下同)乙酸溶液、5%NaCl+4%乙酸混合溶液等3种食物模拟溶液中进行电化学试验,研究了敏化度、浸泡时间和溶液温度对试样耐腐蚀性能的影响。结果表明:在NaCl溶液中,试样的自腐蚀电位随敏化度的增大正移,随浸泡时间的延长先负移后正移;在乙酸溶液和NaCl+乙酸混合溶液中,自腐蚀电位随敏化度的增大或浸泡时间的延长均负移,且在NaCl+乙酸混合溶液中的负移幅度均很小;随着溶液温度的升高,试样在3种溶液中的自腐蚀电流密度和腐蚀速率均增大。

       

      Abstract: Electrochemical tests in three food simulation solutions, including 5wt% NaCl solution, 4vol% acetic acid solution and 5wt% NaCl+4vol% acetic acid solution, were conducted on 430 stainless steel specimens after sensitization to different degrees. Effects of sensitization degree, soaking time and solution temperature on corrosion resistance of specimens were studied. The results show that in the NaCl solution, the free corrosion potential of samples shifted positively with increasing sensitization degree while shifted negatively and then positively with increasing soaking time. In acetic acid solution and NaCl+acetic acid mixed solution, the free corrosion potential shifted negatively with increasing sensitization degree or soaking time, and the shift range in NaCl+acetic acid mixed solution was very narrow. With increasing solution temperature, the free corrosion current density and corrorion rate of specimens in three solutions increased.

       

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