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    吴建春, 方园. 薄带连铸B480GNQR耐候钢的腐蚀行为[J]. 机械工程材料, 2019, 43(10): 47-52. DOI: 10.11973/jxgccl201910010
    引用本文: 吴建春, 方园. 薄带连铸B480GNQR耐候钢的腐蚀行为[J]. 机械工程材料, 2019, 43(10): 47-52. DOI: 10.11973/jxgccl201910010
    WU Jianchun, FANG Yuan. Corrosion Behavior of Strip Casting B480GNQR Weathering Steel[J]. Materials and Mechanical Engineering, 2019, 43(10): 47-52. DOI: 10.11973/jxgccl201910010
    Citation: WU Jianchun, FANG Yuan. Corrosion Behavior of Strip Casting B480GNQR Weathering Steel[J]. Materials and Mechanical Engineering, 2019, 43(10): 47-52. DOI: 10.11973/jxgccl201910010

    薄带连铸B480GNQR耐候钢的腐蚀行为

    Corrosion Behavior of Strip Casting B480GNQR Weathering Steel

    • 摘要: 采用72 h周期浸润加速腐蚀试验和电化学测试方法研究了薄带连铸B480GNQR耐候钢在0.01 mol·L-1 NaHSO3溶液中的腐蚀行为,并与B800NQ耐候钢和DOCOL700耐候钢,以及Q345B低碳钢的进行对比。结果表明:薄带连铸B480GNQR耐候钢的单位面积质量损失为11.888 mg·cm-2,相对Q345B低碳钢的腐蚀率为43%;4种裸钢试样中薄带连铸B480GNQR耐候钢的自腐蚀电位最高,耐腐蚀性能最好,其电化学交流阻抗谱表现为具有一个时间常数的单一容抗弧特征;4种带锈层试样中薄带连铸B480GNQR耐候钢的自腐蚀电位最高,耐腐蚀性能最好,其电化学交流阻抗谱表现为高频端的容抗弧及中低频端的近似45°直线段的扩散弧特征;距薄带连铸B480GNQR耐候钢铸带表面150~200 μm处磷元素含量最高,呈典型的磷元素负偏析现象,因此大大提高了其耐腐蚀性能。

       

      Abstract: Corrosion behavior of strip casting B480GNQR weathering steel was studied by 72 h alternate immersion accelerated corrosion test and electrochemical test in 0.01 mol·L-1 NaHSO3 solution, and compared with those of B800NQ weathering steel and DOCOL700 weathering steel as well as low carbon Q345B steel. The results show that the loss of mass per unit area of strip casting B480GNQR weathering steel was 11.888 mg·cm-2 and the corrosion rate was 43% relative to low carbon Q345B steel. Strip casting B480GNQR weathering steel among the four bare steel samples had the highest free corrosion potential, indicating that it had the best corrosion resistance; its electrochemical impedance spectroscopy was characterized by the single capacitance resistance arc with a time constant. Strip casting B480GNQR weathering steel among the four rusty steel samples had the highest free corrosion potential, indicating that it had the best corrosion resistance; its electrochemical impedance spectroscopy was characterized by a capacitance resistance arc at the high frequency end and a diffusion arc of approximate 45° segment at the middle and low frequency ends. Phosphorus content at the location of 150~200 μm away from strip casting B480GNQR weathering steel casting band surface was the highest, showing typical negative segregation of phosphorus element, which greatly promoted the corrosion resistance.

       

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