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    700℃先进超超临界机组末级过热器用新型镍铁基高温合金的组织与性能

    Microstructure and Properties of Ni-Fe-base Superalloy for 700 ℃ Advanced Ultra Supercritical Unit Final Superheater

    • 摘要: 研究了700 ℃先进超超临界(A-USC)机组末级过热器用新型镍铁基HT700T高温合金的组织和性能。结果表明:HT700T合金为析出强化型合金,在750 ℃的组织稳定性较好;合金在750 ℃时的屈服强度为598 MPa,且热暴露3 000 h后其屈服强度仍约为400 MPa;合金在750 ℃/105 h的持久强度为103 MPa;在750 ℃热暴露104 h后,室温冲击功为50 J·cm-2,较热暴露前的略有下降;合金的750 ℃抗蒸汽氧化性能达到完全抗氧化级,在750 ℃/2×105 h模拟烟灰/烟气条件下的金属腐蚀深度约为0.2 mm;HT700T合金的综合性能基本满足700 ℃ A-USC机组末级过热器的服役性能要求,其工业试制锅炉管已在试验平台上正常运行超过15 000 h。

       

      Abstract: The microstructure and properties of a new Ni-Fe-base HT700T superalloy for 700℃ A-USC unit final superheater were studied. The results show that HT700T alloy was a precipitation-hardening alloy, and the microstructure stability of HT700T alloy at 750℃ was stable. The yield strength at 750℃ was 598 MPa, and remained about 400 MPa after thermal exposure for 3 000 h. The creep rupture strength of the alloy at 750℃/105 h was 103 MPa. The impact energy at room temperature of the alloy after thermal exposure at 750℃ for 104 h was 50 J·cm-2, which was slightly lower than that before thermal exposure. The resistance to steam oxidation at 750℃ reached the complete oxidation resistance level, and the metal corrosion thickness in simulated flue gas and coal ash at 750℃/2×105 h was 0.2 mm. The comprehensive performance of HT700T alloy could basically meet the service performance requirements of 700℃ A-USC unit final superheater; the industrial manufactured alloy boiler tube had been running normally on the test platform for over 15 000 h.

       

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