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    铁替代部分锰对MnCoGe1.02合金马氏体相变和磁性能的影响

    Effects of Fe Substitution for Partial Mn on Martensitic Transformation and Magnetic Properties of MnCoGe1.02 Alloy

    • 摘要: 利用铁替代MnCoGe1.02合金中部分锰,采用电弧熔炼方法制备了Mn1-xFexCoGe1.02x=0,0.01,0.03,0.06,0.09)合金,研究了合金的物相组成、晶体结构、马氏体相变和磁热效应。结果表明:用铁替代部分锰后,合金的晶格参数和晶胞体积均随铁含量的升高基本呈降低趋势,室温下MnCoGe1.02合金呈正交马氏体和六角奥氏体的两相结构,x=0.01和x=0.03时合金均为单一的正交马氏体相结构,x=0.06和x=0.09时合金为单一的六角奥氏体相结构;合金的马氏体相变温度随铁含量的增加先升高后降低,x=0.03时合金的相变温度最高;铁的添加有效提高了合金的磁化强度差,x=0.03时合金具有最大的磁化强度差,且在5 T、315 K时该合金的磁熵变最大,为18.7 J·K-1·kg-1,说明该合金具有较大的磁热效应。

       

      Abstract: Mn1-xFexCoGe1.02(x=0,0.01,0.03,0.06,0.09) alloy was prepared by arc smelting method using Fe to replace part of Mn in MnCoGe1.02 alloy, and the phase composition, crystal structure, martensitic transformation and magnetothermal effect of the alloy were studied.The results show that after replacing part of Mn with Fe, the lattice parameters and cell volume of the alloy basically showed a decreasing trend with increasing iron content. MnCoGe1.02 alloy at room temperature showed a coexisted structure with orthogonal martensite phase and hexagonal austenite phase. The alloys with x=0.01 and x=0.03 were both single orthogonal martensite phase structure. The alloys with x=0.06 and x=0.09 were both single hexagonal austenitic phase structure. The temperature of martensitic transformation increased first and then decreased with increasing Fe content, and the alloy with x=0.03 had the highest transformation temperature. The addition of Fe effectively improved the intensity difference of magnetization of the alloy. The alloy with x=0.03 had the largest intensity difference of magnetization, and at 5 T and 315 K, the alloy had the largest magnetic entropy change of 18.7 J·K-1·kg-1, indicating that the alloy had the relatively large magneto-thermal effect.

       

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