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    镧掺杂量对Pb(1-2x/3)Lax(Ti0.99Mn0.01)O3压电陶瓷性能的影响

    Effect of Lanthanum Doping Amounts on Properties ofPb<sub>(1-2x/3)Lax(Ti0.99Mn0.01)O3 Piezoelectric Ceramics

    • 摘要: 采用固相烧结法制备了Pb(1-2x/3)Lax(Ti0.99Mn0.01)O3压电陶瓷,研究了镧掺杂量(x=0.005,0.045,0.075,0.150,物质的量分数)对压电陶瓷晶格常数、压电各向异性、介电常数、介电损耗、居里温度以及机械品质因数的影响。结果表明:随着镧掺杂量增加,压电陶瓷晶格的轴向比(c/a)减小,各向异性和四方相结构减弱,介电损耗减小,机械品质因数增大;镧的掺杂有利于压电性能的改善,但会造成压电各向异性减弱,居里温度降低,介电常数增大。

       

      Abstract: Pb<sub>(1-2x/3)Lax(Ti0.99Mn0.01)O3 piezoelectric ceramics were prepared by solid-phase sintering method. The effects of lanthanum doping amount (x=0.005,0.045,0.075,0.150,mole fraction) on the lattice constant, piezoelectric anisotropy, dielectric constant, dielectric loss, Curie temperature and mechanical quality factor of the piezoelectric ceramics were studied. The results show that with increasing lanthanum doping amount, the axial ratio of the lattice (c/a) of the piezoelectric ceramics decreased, the anisotropy and the tetragonal structure was weakened, the dielectric loss was reduced, and the mechanical quality factor increased. The La doping was helpful for the improvement of the piezoelectric property, but resulted in the decrease of the piezoelectric anisotropy and the Curie temperature and the increase of the dielectric constant.

       

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