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    张凯丽, 谢飞, 吴明, 王丹, 盖左松, 刘晋. 腐蚀产物膜对X70管线钢焊缝海底腐蚀行为的影响[J]. 机械工程材料, 2021, 45(7): 12-16,40. DOI: 10.11973/jxgccl202107003
    引用本文: 张凯丽, 谢飞, 吴明, 王丹, 盖左松, 刘晋. 腐蚀产物膜对X70管线钢焊缝海底腐蚀行为的影响[J]. 机械工程材料, 2021, 45(7): 12-16,40. DOI: 10.11973/jxgccl202107003
    ZHANG Kaili, XIE Fei, WU Ming, WANG Dan, GAI Zuosong, LIU Jin. Effect of Corrosion Product Film on Seabed Corrosion Behavior of X70 Pipeline Steel Weld[J]. Materials and Mechanical Engineering, 2021, 45(7): 12-16,40. DOI: 10.11973/jxgccl202107003
    Citation: ZHANG Kaili, XIE Fei, WU Ming, WANG Dan, GAI Zuosong, LIU Jin. Effect of Corrosion Product Film on Seabed Corrosion Behavior of X70 Pipeline Steel Weld[J]. Materials and Mechanical Engineering, 2021, 45(7): 12-16,40. DOI: 10.11973/jxgccl202107003

    腐蚀产物膜对X70管线钢焊缝海底腐蚀行为的影响

    Effect of Corrosion Product Film on Seabed Corrosion Behavior of X70 Pipeline Steel Weld

    • 摘要: 将X70管线钢焊缝在模拟南海海泥溶液中浸泡腐蚀10,24,72,120 h后,通过扫描电镜和能谱仪分析了其表面腐蚀产物的形貌及组成,通过慢应变速率拉伸试验和动电位极化试验研究了腐蚀产物膜对焊缝腐蚀行为的影响。结果表明:随着腐蚀时间的延长,焊缝表面腐蚀产物膜逐渐增厚,腐蚀72 h时形成致密的腐蚀产物膜,腐蚀120 h后膜中产生较多孔洞和裂纹;随着腐蚀时间的延长,焊缝的应力腐蚀敏感性呈现先增大再减小再增大的趋势,电化学腐蚀性能的变化趋势相同;腐蚀72 h时,致密腐蚀产物膜的形成降低了焊缝的应力腐蚀敏感性,提高了其耐腐蚀性能。

       

      Abstract: After corrosion in simulated South China Sea mud solution for 10, 24, 72, 120 h, the morphology and composition of the corrosion products on surface of the weld of X70 pipeline steel were analyzed by scanning electron microscopy and energy spectroscopy. Then the effect of corrosion product film on the corrosion behavior of the weld was studied by slow strain rate tensile tests and potentiodynamic polarization tests. The results show that with increasing corrosion time, the corrosion product films on surface of the weld were thickened. A dense corrosion product film was formed after corrosion for 72 h, and more pores and cracks were formed in the film after 120 h corrosion. With increasing corrosion time, the stress corrosion sensitivity of the weld increased first, then decreased, and then slightly increased. The electrochemical corrosion behavior showed the same change. After corrosion for 72 h, the formation of the dense corrosion product film reduced the stress corrosion sensitivity of the weld and improved the corrosion resistance.

       

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