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    连接温度对CaO-Al2O3-MgO-SiO2-TiO2玻璃钎料连接SiC陶瓷接头微观结构和性能的影响

    Effect of Joining Temperature on Microstructure and Properties of SiC Ceramic Joints with CaO-Al2O3-MgO-SiO2-TiO2 Glass Solder

    • 摘要: 采用新型玻璃钎料CaO-Al2O3-MgO-SiO2-TiO2(CAMST)连接无压烧结SiC陶瓷,研究了连接温度(1 300~1 450℃)对SiC陶瓷接头微观结构和力学性能的影响。结果表明:CAMST玻璃钎料在1 350~1 450℃下可实现SiC陶瓷的有效连接。当连接温度为1 350℃时,焊缝厚度约为36 μm,母材与焊缝界面存在较多孔洞,接头剪切强度为(21.4±2.7) MPa;当连接温度为1 400℃时,焊缝厚度为3 μm,母材与焊缝结合良好,接头剪切强度为(47.6±6.2) MPa;当连接温度升高至1 450℃时,焊缝厚度约为50 μm,母材与焊缝结合良好,但焊缝中存在裂纹缺陷,接头剪切强度为(20.9±3.9) MPa。连接温度对焊缝硬度无明显影响。

       

      Abstract: Pressureless sintered SiC ceramics were joined with a noval glass solder of CaO-Al2O3-MgO-SiO2-TiO2 (CAMST). The effect of joining temperature (1 300-1 450℃) on the microstructure and mechanical properties of SiC ceramic joints was investigated. The results show that CAMST glass solder could effectively connect SiC ceramics at 1 350-1 450℃. The thickness of the weld was about 36 μm when the joining temperature was 1 350℃, and large pores were observed in the interlayer between base metal and weld; the shear strength of the joint was (21.4±2.7) MPa. When the joining temperature was 1 400℃, the thickness of the weld was about 3 μm, and the base metal was well bonded with weld; the shear strength of the joint was (47.6±6.2) MPa. When the joining temperature was 1 450℃, the thickness of the weld was about 50 μm; the base metal was well bonded with weld, but there were crack defects in the weld; the shear strength of the joint was (20.9±3.9) MPa. The joining temperature had no significant effect on the hardness of the weld.

       

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