Influence of Canbon Content on Microstructure and Properties of CxCrFeMnNi High-Entropy Alloy Cladding Layer Fabricated by Plasma Transferred Arc
-
摘要: 采用等离子转移弧焊制备了CxCrFeMnNi(x=0.2,0.4,0.6,0.8,1.0,物质的量比)高熵合金熔覆层,研究了碳含量对熔覆层的宏观形貌、物相组成、显微组织和性能的影响。结果表明:当x为0.4,0.8,1.0 时,熔覆层成形质量较好,无明显的气孔、凹坑、黏粉等缺陷;CxCrFeMnNi高熵合金熔覆层组织均包含FCC树枝晶和(Cr,Fe)C碳化物,当x为0.6~1.0时,还析出了Cr7C3碳化物;随着碳含量增加,碳化物含量增加,熔覆层的平均显微硬度升高,摩擦因数和磨损量均减小;当x为1.0时,熔覆层的平均硬度最高,为368 HV,摩擦因数和磨损量最小,分别为0.541和1.38 mg。Abstract: CxCrFeMnNi (x=0.2,0.4,0.6,0.8,1.0,mole ratio) high-entropy alloy cladding layers were prepared by plasma transferred arc welding. The effects of carbon content on the macroscopic morphology, phase composition, microstructure and properties of the cladding layer were studied. The results show that when x was 0.4, 0.8 and 1.0, the forming quality of the cladding layer was relatively good, and there were no obvious defects such as pores, pits and sticky powder. The microstructure of CxCrFeMnNi high-entropy alloy cladding layer consisted of FCC dendrites and (Cr, Fe) C carbide, and Cr7C3 carbide was also precipitated when x was 0.6-1.0. With the increase of carbon content, the carbide content and the average microhardness of the cladding layer increased, and the friction coefficient and wear amount decreased. When x was 1.0, the average hardness of the cladding layer was the highest of 368 HV, and the friction coefficient and wear amount were the smallest of 0.541 and 1.38 mg, respectively.
-
-
[1] CANTOR B,CHANG I T H,KNIGHT P,et al.Microstructural development in equiatomic multicomponent alloys[J].Materials Science and Engineering:A,2004,375/376/377:213-218.
[2] YEH J W,CHEN S K,LIN S J,et al.Nanostructured high-entropy alloys with multiple principal elements:Novel alloy design concepts and outcomes[J].Advanced Engineering Materials,2004,6(5):299-303.
[3] PICKERING E J,JONES N G.High-entropy alloys:A critical assessment of their founding principles and future prospects[J].International Materials Reviews,2016,61(3):183-202.
[4] BHATTACHARJEE T,ZHENG R X,CHONG Y,et al.Effect of low temperature on tensile properties of AlCoCrFeNi2.1 eutectic high entropy alloy[J].Materials Chemistry and Physics,2018,210:207-212.
[5] YU P F,ZHANG L J,CHENG H,et al.The high-entropy alloys with high hardness and soft magnetic property prepared by mechanical alloying and high-pressure sintering[J].Intermetallics,2016,70:82-87.
[6] 魏耀光,郭刚,李静,等.难熔高熵合金在航空发动机上的应用[J].航空材料学报,2019,39(5):82-93. WEI Y G,GUO G,LI J,et al.Application of refractory high entropy alloys on aero-engines[J].Journal of Aeronautical Materials,2019,39(5):82-93.
[7] LI Z M,PRADEEP K G,DENG Y,et al.Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off[J].Nature,2016,534:227-230.
[8] YAN X L,GUO H,YANG W,et al.Al0.3CrxFeCoNi high-entropy alloys with high corrosion resistance and good mechanical properties[J].Journal of Alloys and Compounds,2021,860:158436.
[9] HE J Y,WANG H,HUANG H L,et al.A precipitation-hardened high-entropy alloy with outstanding tensile properties[J].Acta Materialia,2016,102:187-196.
[10] WANG Z W,BAKER I,GUO W,et al.The effect of carbon on the microstructures,mechanical properties,and deformation mechanisms of thermo-mechanically treated Fe40.4Ni11.3Mn34.8Al7.5Cr6 high entropy alloys[J].Acta Materialia,2017,126:346-360.
[11] WANG Y J,SUN J J,JIANG T,et al.A low-alloy high-carbon martensite steel with 2.6 GPa tensile strength and good ductility[J].Acta Materialia,2018,158:247-256.
[12] BOWDEN D,KRYSIAK Y,PALATINUS L,et al.A high-strength silicide phase in a stainless steel alloy designed for wear-resistant applications[J].Nature Communications,2018,9:1374.
[13] HU C H,ZHANG J L,ZHANG Y H,et al.A great enhancement of both strength and plasticity in a dual-phase high-entropy alloy by multi-effects of high carbon addition[J].Materials & Design,2023,225:111571.
[14] XIAO J K,TAN H,CHEN J,et al.Effect of carbon content on microstructure,hardness and wear resistance of CoCrFeMnNiCx high-entropy alloys[J].Journal of Alloys and Compounds,2020,847:156533.
[15] YANG J P,JIANG L W,LIU Z H,et al.Multifunctional interstitial-carbon-doped FeCoNiCu high entropy alloys with excellent electromagnetic-wave absorption performance[J].Journal of Materials Science & Technology,2022,113:61-70.
[16] JEYAPRAKASH N,PRABU G,YANG C H.Microstructure and tribological behaviour of FeCoCrNiAlCuMn particles alloyed on Inconel-718 substrate using plasma transferred arc technique[J].Intermetallics,2021,139:107360.
[17] 饶湖常,戴品强,陈鼎宁,等.碳含量对FeCoCrNiMnCx高熵合金显微组织与性能的影响[J].机械工程材料,2016,40(8):76-80. RAO H C,DAI P Q,CHEN D N,et al.Effects of carbon content on microstructure and properties of FeCoCrNiMnCx high-entropy alloys[J].Materials for Mechanical Engineering,2016,40(8):76-80.
[18] TAKEUCHI A,INOUE A.Classification of bulk metallic glasses by atomic size difference,heat of mixing and period of constituent elements and its application to characterization of the main alloying element[J].Materials Transactions,2005,46(12):2817-2829.
[19] ZHANG Y,ZHOU Y,LIN J,et al.Solid-solution phase formation rules for multi-component alloys[J].Advanced Engineering Materials,2008,10(6):534-538.
[20] LI X F,FENG Y H,WANG X,et al.Microstructures and properties of AlCrFeNiMnx high-entropy alloy coatings fabricated by laser cladding on a copper substrate[J].Journal of Alloys and Compounds,2022,926:166778.
计量
- 文章访问数: 1
- HTML全文浏览量: 0
- PDF下载量: 3