掺杂Y<sub>2</sub>O<sub>3</sub>钨基复合材料在近韧脆转变温区的静载拉伸特性

黄俊; 李阳阳; 袁国虎; 左彤; 罗来马; 徐光青; 吕珺; 谭晓月; 洪雨; 朱晓勇; 吴玉程

doi:10.11973/jxgccl202311004

掺杂Y₂O₃钨基复合材料在近韧脆转变温区的静载拉伸特性

黄俊^1,2,3,4,
李阳阳¹,
袁国虎¹,
左彤¹,
罗来马^1,2,3,4,
徐光青^1,2,3,
吕珺^1,2,3,
谭晓月^1,2,
洪雨^1,3,
朱晓勇^1,2,3,4,
吴玉程^1,2,3,4,

1. 合肥工业大学材料科学与工程学院, 合肥 230009;
2. 合肥工业大学有色金属与加工技术国家地方联合工程研究中心, 合肥 230009;
3. 合肥工业大学先进功能材料与器件安徽省重点实验室, 合肥 230009;
4. 合肥工业大学先进能源与环境材料国际科技合作基地, 合肥 230009

基金项目:

国家自然科学基金国际（地区）合作研究与交流项目（52020105014）

详细信息

作者简介:
黄俊(1983-),女,安徽安庆人,副教授,博士

通讯作者:
吴玉程教授

中图分类号: TG146.4
计量
- 文章访问数: 10
- HTML全文浏览量: 0
- PDF下载量: 4
出版历程
- 收稿日期: 2022-06-22
- 修回日期: 2023-08-01
- 刊出日期: 2023-11-19

Static Tensile Properties near Ductile-Brittle Transition Temperature Region of W-based Composites Doped with Y₂O₃

HUANG Jun^1,2,3,4,
LI Yangyang¹,
YUAN Guohu¹,
ZUO Tong¹,
LUO Laima^1,2,3,4,
XU Guangqing^1,2,3,
LYU Jun^1,2,3,
TAN Xiaoyue^1,2,
HONG Yu^1,3,
ZHU Xiaoyong^1,2,3,4,
WU Yucheng^1,2,3,4,

1. School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China;
2. National-Local Joint Engineering Research Centre ofNonferrous Metals and Processing Technology, Hefei University of Technology, Hefei 230009, China;
3. Key Laboratory of Advanced Functional Materials andDevices of Anhui Province, Hefei University of Technology, Hefei 230009, China;
4. International S & T Cooperation Base for Advanced Energy and Environmental Materials, Hefei University of Technology, Hefei 230009, China

摘要

摘要: 制备了掺杂质量分数分别为0.5%，2.0% Y₂O₃的钨基复合材料，研究了其显微组织，通过不同温度（25~800℃）下的拉伸试验分析了其近韧脆转变温区的变形特性。结果表明：2种复合材料均存在由轧制变形导致的大量位错，Y₂O₃颗粒对位错运动起到钉扎作用；Y₂O₃掺杂质量分数为2.0%的复合材料的晶粒更细小，发生韧脆转变的温度更低，在300~400℃拉伸时发生半脆性行为，断口区域位错密度在3.8×10¹⁵~3.9×10¹⁵ m^-2，在600~800℃下发生明显塑性变形，位错密度增加至6.2×10¹⁵~6.8×10¹⁵ m^-2。
- Y₂O₃ /
- 钨基复合材料 /
- 韧脆转变温度 /
- 显微组织
Abstract: W-based composites doped with 0.5wt% and 2.0wt% Y₂O₃ were prepared. The microstructure of the composites was investigated. The deformation characteristics near ductile-brittle transition temperature region of the composites were analyzed by tensile tests at different temperatures (25-800℃). The results show that the two composites had a large number of dislocations formed by rolling deformation, and Y₂O₃ particles played a pinning role in dislocation motion. The composite containing 2.0wt% Y₂O₃ had smaller grain size and a lower ductile-brittle transition temperature. The semi-brittle behavior of the composite containing 2.0wt% Y₂O₃ occurred during tension at 300-400℃, and the dislocation density in the fracture area was between 3.8×10¹⁵-3.9×10¹⁵ m^-2; during tension at 600-800℃, plastic deformation occurred, and the dislocation density increased to 6.2×10¹⁵-6.8×10¹⁵ m^-2.
- Y₂O₃ /
- W-based composite /
- ductile-brittle transition temperature /
- microstructure

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参考文献(32)

[1]	李建刚.托卡马克研究的现状及发展[J].物理,2016,45(2):88-97. LI J G.The status and progress of tokamak research[J].Physics,2016,45(2):88-97.
[2]	周张健,钟志宏,沈卫平,等.聚变堆中面向等离子体材料的研究进展[J].材料导报,2005,19(12):5-8. ZHOU Z J,ZHONG Z H,SHEN W P,et al.The development of plasma facing materials for fusion reactor[J].Materials Review,2005,19(12):5-8.
[3]	BACHMANN C,AIELLO G,ALBANESE R,et al.Initial DEMO tokamak design configuration studies[J].Fusion Engineering and Design,2015,98/99:1423-1426.
[4]	LIBEYRE P,SCHILD T,BRUTON A,et al.From manufacture to assembly of the ITER central solenoid[J].Fusion Engineering and Design,2019,146:437-440.
[5]	HILL D N.A review of ELMs in divertor tokamaks[J].Journal of Nuclear Materials,1997,241/242/243:182-198.
[6]	BOLT H,BARABASH V,KRAUSS W,et al.Materials for the plasma-facing components of fusion reactors[J].Journal of Nuclear Materials,2004,329/330/331/332/333:66-73.
[7]	COENEN J W,ANTUSCH S,AUMANN M,et al.Materials for DEMO and reactor applications:Boundary conditions and new concepts[J].Physica Scripta,2016,T167:014002.
[8]	LINSMEIER C,RIETH M,AKTAA J,et al.Development of advanced high heat flux and plasma-facing materials[J].Nuclear Fusion,2017,57(9):092007.
[9]	HATANO Y,AMI K,ALIMOV V K,et al.Deuterium retention in W and W-Re alloy irradiated with high energy Fe and W ions:Effects of irradiation temperature[J].Nuclear Materials and Energy,2016,9:93-97.
[10]	WANG C J,DONG X N,WEI S Z,et al,Effect of hot-working process on interface structure and ductile-to-brittle transition temperature of tungsten alloy reinforced by Al₂O₃ particles[J].International Journal of Refractory Metals and Hard Materials,2022,108:105945.
[11]	YAO G,ZHAO Z H,LUO L M,et al.Damage evolutions of completely recrystallized W-Y₂O₃ composite evaluated using the dual effects of electron beam thermal shock and helium ion irradiation[J].Materials Chemistry and Physics,2021,271:124947.
[12]	YAO G,TAN X Y,LUO L M,et al.Influence of helium ion irradiation damage behavior after laser thermal shock of W-2%vol Y₂O₃ composites[J].Progress in Nuclear Energy,2020,121:103241.
[13]	DONG Z,MA Z Q,YU L M,et al.Enhanced mechanical properties in oxide-dispersion-strengthened alloys achieved via interface segregation of cation dopants[J].Science China Materials,2021,64(4):987-998.
[14]	DONG Z,MA Z Q,YU L M,et al.Nanoscale segregation mechanism of cation dopant at the matrix/oxide interface in oxide dispersion-strengthened alloys[J].Journal of Materials Science,2021,56(10):6251-6268.
[15]	HUANG L,JIANG L,TOPPING T D,et al.In situ oxide dispersion strengthened tungsten alloys with high compressive strength and high strain-to-failure[J].Acta Materialia,2017,122:19-31.
[16]	XU Q,DING X Y,LUO L M,et al.Thermal stability and evolution of microstructures induced by He irradiation in W-TiC alloys[J].Nuclear Materials and Energy,2018,15:76-79.
[17]	LANG S T,YAN Q Z,SUN N B,et al.Microstructure,basic thermal-mechanical and Charpy impact properties of W-0.1wt.% TiC alloy via chemical method[J].Journal of Alloys and Compounds,2016,660:184-192.
[18]	ZHANG Y,GANEEV V A,WANG T J,et al,Observations on the ductile-to-brittle transition in ultrafine-grained tungsten of commercial purity[J].Materials Science & Engineering A,2008,503(1):37-40.
[19]	LEVIN Z S,HARTWIG K T.Strong ductile bulk tungsten[J].Materials Science and Engineering:A,2017,707:602-611.
[20]	RIESCH J,AUMANN M,COENEN J W,et al.Chemically deposited tungsten fibre-reinforced tungsten:The way to a mock-up for divertor applications[J].Nuclear Materials and Energy,2016,9:75-83.
[21]	MAO Y,COENEN J W,RIESCH J,et al.Influence of the interface strength on the mechanical properties of discontinuous tungsten fiber-reinforced tungsten composites produced by field assisted sintering technology[J].Composites Part A:Applied Science and Manufacturing,2018,107:342-353.
[22]	YE J H,XU L J,ZHAO Y C,et al.DBTT and tensile properties of as-sintered tungsten alloys reinforced by yttrium-zirconium oxide[J]. Journal of Nuclear Materials,2023,578:154318.
[23]	XIE Z M,LIU R,MIAO S,et al.Extraordinary high ductility/strength of the interface designed bulk W-ZrC alloy plate at relatively low temperature[J]. Scientific reports,2015,5(1):16014.
[24]	SCAPIN M,PERONI L,TORREGROSA C,et al.Effect of strain-rate and temperature on mechanical response of pure tungsten[J].Journal of Dynamic Behavior of Materials,2019,5(3):296-308.
[25]	YAO G,TAN X Y,FU M Q,et al.Isotropic thermal conductivity in rolled large-sized W-Y₂O₃ bulk material prepared by powder metallurgy route and rolling deformation technology[J].Fusion Engineering and Design,2018,137:325-330.
[26]	MOTE V,PURUSHOTHAM Y,DOLE B.Williamson-Hall analysis in estimation of lattice strain in nanometer-sized ZnO particles[J].Journal of Theoretical and Applied Physics,2012,6(1):6.
[27]	郭宁.桥梁缆索用冷拔珠光体钢丝微观组织表征及力学性能研究[D].重庆:重庆大学,2012. GUO N.Microstructure characterization and mechanical properties of cold-drawn pearlite steel wire for bridge cables[D].Chongqing:Chongqing University,2012.
[28]	ZHANG Y F,JI Z,JIA C C,et al.Influence of lanthanum on enhancement of mechanical and electrical properties of Cu-Al₂O₃ composites[J].Journal of Rare Earths,2019,37(5):534-540.
[29]	SHEN T L,DAI Y,LEE Y.Microstructure and tensile properties of tungsten at elevated temperatures[J].Journal of Nuclear Materials,2016,468:348-354.
[30]	NAGY D,HUMPHRY-BAKER S A.An oxidation mechanism map for tungsten[J].Scripta Materialia,2022,209:114373.
[31]	DU W B,YAO Z J,TAO X W,et al.Oxidation behavior and mechanism of directional order two-scale lamellar porous Ti₃SiC₂ compound[J].Journal of Alloys and Compounds,2022,927:166998.
[32]	SAMAEE V,GATTI R,DEVINCRE B,et al.Dislocation driven nanosample plasticity:New insights from quantitative in situ TEM tensile testing[J].Scientific Reports,2018,8:12012.