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    周浪, 陈猛, 谭东灿, 苏玉琴, 钟钢, 邹爱华, 李志鹏. 石墨烯化学镀铜对放电等离子烧结石墨烯增强铝基复合材料组织和性能的影响[J]. 机械工程材料, 2024, 48(7): 55-62. DOI: 10.11973/jxgccl230181
    引用本文: 周浪, 陈猛, 谭东灿, 苏玉琴, 钟钢, 邹爱华, 李志鹏. 石墨烯化学镀铜对放电等离子烧结石墨烯增强铝基复合材料组织和性能的影响[J]. 机械工程材料, 2024, 48(7): 55-62. DOI: 10.11973/jxgccl230181
    ZHOU Lang, CHEN Meng, TAN Dongcan, SU Yuqin, ZHONG Gang, ZOU Aihua, LI Zhipeng. Effect of Graphene Electroless Copper Plating on Microstructure and Properties of Spark Plasma Sintering Graphene Reinforced Aluminum Matrix Composites[J]. Materials and Mechanical Engineering, 2024, 48(7): 55-62. DOI: 10.11973/jxgccl230181
    Citation: ZHOU Lang, CHEN Meng, TAN Dongcan, SU Yuqin, ZHONG Gang, ZOU Aihua, LI Zhipeng. Effect of Graphene Electroless Copper Plating on Microstructure and Properties of Spark Plasma Sintering Graphene Reinforced Aluminum Matrix Composites[J]. Materials and Mechanical Engineering, 2024, 48(7): 55-62. DOI: 10.11973/jxgccl230181

    石墨烯化学镀铜对放电等离子烧结石墨烯增强铝基复合材料组织和性能的影响

    Effect of Graphene Electroless Copper Plating on Microstructure and Properties of Spark Plasma Sintering Graphene Reinforced Aluminum Matrix Composites

    • 摘要: 通过化学镀方法得到镀铜石墨烯粉末,再通过静电自组装方法将镀铜石墨烯粉末与铝粉混合,然后经放电等离子烧结工艺制备镀铜石墨烯增强铝基复合材料,研究了不同质量分数(0.1%,0.2%,0.3%,0.4%,0.5%)镀铜石墨烯增强铝基复合材料的微观结构和性能,并与质量分数0.1%未镀铜石墨烯增强铝基复合材料进行对比。结果表明:镀铜石墨烯在复合材料中分散均匀,复合材料的相对密度均在99%以上;铝和铜发生反应生成了中间相Al2Cu,但未有Al4C3界面相生成;镀铜石墨烯增强铝基复合材料的硬度和耐磨性能均优于未镀铜石墨烯增强铝基复合材料;随着镀铜石墨烯含量的增加,复合材料的硬度先升高后降低,磨损质量损失和摩擦因数均呈先减小后增加的趋势。当镀铜石墨烯的质量分数为0.2%时,复合材料具有优异的综合性能,其硬度为74.7 HV,磨损质量损失和摩擦因数均最小,分别为0.002 3 g和0.259,磨损机制为氧化磨损。

       

      Abstract: Copper-plated graphene powder was obtained by electroless plating, and then was mixed with aluminum powder by electrostatic self-assembly. The copper-plated graphene reinforced aluminum matrix composite was prepared by spark plasma sintering. The microstructure and properties of different mass fractions (0.1%,0.2%,0.3%,0.4%,0.5%) of copper-plated graphene reinforced aluminum matrix composites were investigated, and were compared with those of 0.1wt% uncopper-plated graphene reinforced aluminum matrix composite. The results show that the copper-plated graphene was uniformly dispersed in the composites, and the relative density of the composites was more than 99%. Aluminum reacted with copper to form the intermediate phase Al2Cu, but no Al4C3 interfacial phase was formed. The hardness and wear resistance of the copper-plated graphene reinforced aluminum matrix composites were better than those of the uncopper-plated graphene reinforced aluminum matrix composites. With the increase of copper-plated graphene content, the hardness of the composites first increased and then decreased, and the wear mass loss and friction coefficient first decreased and then increased. When the mass fraction of copper-plated graphene was 0.2%, the composite had excellent comprehensive properties with hardness of 74.7 HV, and the smallest wear mass loss and friction coefficient of 0.002 3 g and 0.259, respectively, and the wear mechanism was oxidation wear.

       

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