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    阻垢剂和CO2对J55钢在油田模拟采出水中腐蚀行为的影响

    Effect of Scale Inhibitor and CO2 on Corrosion Behavior of J55 Steel in Oil Field Simulated Produced Water

    • 摘要: 通过浸泡腐蚀和电化学腐蚀测试,研究了J55钢在不含阻垢剂和CO2、只含CO2、只含阻垢剂和同时含阻垢剂和CO2条件下的油田模拟采出水中的均匀腐蚀和点腐蚀行为。结果表明:在不含阻垢剂和CO2条件下,J55钢的均匀腐蚀速率较低,最大点蚀速率最高;相较于不含阻垢剂和CO2条件,只含CO2条件下该钢的均匀腐蚀速率升高,但最大点蚀速率降低,只含阻垢剂条件下该钢的均匀腐蚀速率和最大点蚀速率均降低;在同时含CO2和阻垢剂条件下,该钢的均匀腐蚀速率最高,最大点蚀速率较不含阻垢剂和CO2条件有所降低。当体系中存在CO2时,该钢表面主要生成CaCO3或CaMg(CO32结垢物。同时含CO2和阻垢剂条件下,阻垢剂能抑制结垢过程,改变腐蚀产物膜和结垢物的结构,失去对基体的保护作用。

       

      Abstract: The uniform corrosion and pitting corrosion behavior of J55 steel was studied in oil field simulated produced water without scale inhibitor and CO2, with CO2, with scale inhibitor and with both scale inhibitor and CO2 through immersion corrosion and electrochemical corrosion tests. The results show that under the condition without scale inhibitor and CO2, the uniform corrosion rate of J55 steel was relatively low, and the maximum pitting corrosion rate was the highest. Compared to those without scale inhibitor and CO2, the uniform corrosion rate of the steel increased and the maximum pitting corrosion rate decreased under the condition with CO2, and both decreased under the condition with scale inhibitor. Under the condition with both CO2 and scale inhibitor, the uniform corrosion rate of the steel was the highest, and the maximum pitting corrosion rate was lower than that without scale inhibitor and CO2. When CO2 was present in the system, CaCO3 or CaMg(CO3)2 scaling products were mainly formed on the surface of the steel. Under the condition with both CO2 and scale inhibitor, scale inhibitor would inhibit the scaling process, change the structure of corrosion products and scale deposits, and lost the protective effect on the matrix.

       

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