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    埋粉组成对多孔Si3N4陶瓷结构和性能的影响

    Effect of Composition of Buried Powder on Structure and Properties of Porous Si3N4 Ceramics

    • 摘要: 利用凝胶注模成型工艺制备α-Si3N4陶瓷素坯,并分别埋在BN、BN+Y2O3+Al2O3(物质的量比1∶1∶1)、BN+Y2O3+Al2O3+Si3N4(物质的量比1∶1∶1∶1)的粉床中,采用气压烧结工艺制备多孔Si3N4陶瓷,研究了埋粉组成对陶瓷物相组成、微观结构、抗弯强度和介电性能的影响。结果表明:利用BN埋粉烧结得到的多孔Si3N4陶瓷由α-Si3N4颗粒组成,孔隙率最高,抗弯强度和介电常数最低;利用BN+Y2O3+Al2O3埋粉烧结得到的陶瓷主要由颗粒状α-Si3N4组成,少量短柱状β-Si3N4相分散在α-Si3N4中,孔隙率较高,抗弯强度和介电常数较低;采用BN+Y2O3+Al2O3+Si3N4埋粉烧结得到的陶瓷由长柱状β-Si3N4相组成,β-Si3N4晶粒交叉互锁形成孔洞,孔隙率最低,抗弯强度和介电常数最高。利用不同组成埋粉烧结得到陶瓷的介电损耗均在10−3数量级,陶瓷的透波性能优异。利用BN+Y2O3+Al2O3+Si3N4埋粉烧结得到的多孔Si3N4陶瓷的性能最优,其孔隙率为53.7%,抗弯强度为128.2 MPa,介电常数为2.96,介电损耗为1.62×10−3

       

      Abstract: The α-Si3N4 ceramic green body was prepared by gel injection molding process, and was buried in the powder bed composed of BN, BN+Y2O3+Al2O3 (material ratio of 1∶1∶1), BN+Y2O3+Al2O3+Si3N4 (material ratio of 1∶1∶1), respectively, to prepare porous Si3N4 ceramics by pressure sintering process. The effects of buried powder composition on phase composition, microstructure, bending strength and dielectric properties of ceramics were studied. The results show that the porous Si3N4 ceramics obtained by sintering with BN buried powder were composed of α-Si3N4 particles with the highest porosity and the lowest flexural strength and dielectric constant. The ceramics obtained by sintering with BN+Y2O3+Al2O3 buried powder were mainly composed of granular α-Si3N4 and a small amount of elongated β-Si3N4 dispersed in the α-Si3N4; the porosity was relatively high, and the flexural strength and dielectric constant were relatively low. The ceramics obtained by sintering with BN+Y2O3+Al2O3+Si3N4 buried powder were composed of elongated β-Si3N4, and pores were formed by interlocking of β-Si3N4 grains, resulting in the lowest porosity and the highest flexural strength and dielectric constant. The dielectric loss of ceramics obtained by sintering with different composition buried powder were at the order of 10−3, indicating excellent microwave transmission properties. The porous Si3N4 ceramics sintered with BN+Y2O3+Al2O3+Si3N4 buried powder exhibited the best performance, with the porosity of 53.7%, flexural strength of 128.2 MPa, dielectric constant of 2.96, and dielectric loss of 1.62×10−3.

       

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