Abstract:
The α-Si
3N
4 ceramic green body was prepared by gel injection molding process, and was buried in the powder bed composed of BN, BN+Y
2O
3+Al
2O
3 (material ratio of 1∶1∶1), BN+Y
2O
3+Al
2O
3+Si
3N
4 (material ratio of 1∶1∶1), respectively, to prepare porous Si
3N
4 ceramics by pressure sintering process. The effects of buried powder composition on phase composition, microstructure, bending strength and dielectric properties of ceramics were studied. The results show that the porous Si
3N
4 ceramics obtained by sintering with BN buried powder were composed of α-Si
3N
4 particles with the highest porosity and the lowest flexural strength and dielectric constant. The ceramics obtained by sintering with BN+Y
2O
3+Al
2O
3 buried powder were mainly composed of granular α-Si
3N
4 and a small amount of elongated β-Si
3N
4 dispersed in the α-Si
3N
4; the porosity was relatively high, and the flexural strength and dielectric constant were relatively low. The ceramics obtained by sintering with BN+Y
2O
3+Al
2O
3+Si
3N
4 buried powder were composed of elongated β-Si
3N
4, and pores were formed by interlocking of β-Si
3N
4 grains, resulting in the lowest porosity and the highest flexural strength and dielectric constant. The dielectric loss of ceramics obtained by sintering with different composition buried powder were at the order of 10
−3, indicating excellent microwave transmission properties. The porous Si
3N
4 ceramics sintered with BN+Y
2O
3+Al
2O
3+Si
3N
4 buried powder exhibited the best performance, with the porosity of 53.7%, flexural strength of 128.2 MPa, dielectric constant of 2.96, and dielectric loss of 1.62×10
−3.