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    Sn-0.3Ag-0.7Cu合金焊膏瞬时液相扩散焊接铜接头的界面组织及剪切性能

    Interfacial Microstructure and Shear Property of Copper Joints Bonded with Sn-0.3Ag-0.7Cu Alloy Solder by Transient Liquid Phase Diffusion

    • 摘要: 在两块紫铜基板之间均匀涂覆20 μm厚度Sn-0.3Ag-0.7Cu合金焊膏,在不同回流温度(240,260,280 ℃)和不同回流时间(0,1,2,3,4,8 h)下进行瞬时液相扩散焊试验,研究了不同工艺接头的界面组织和剪切性能。结果表明:在回流温度240 ℃下随着回流时间延长,接头界面的金属间化合物Cu6Sn5先增加后减少,形貌由扇贝状转变为层状;当回流时间为4 h时,焊缝中几乎填满Cu6Sn5,焊缝与母材界面处形成Cu3Sn金属化合物薄层,当回流时间为8 h时焊缝中出现较大孔洞,Cu3Sn金属化合物层厚度增加。界面金属间化合物层的厚度随回流时间延长或回流温度升高先增大后减小,其生长符合体扩散特征,扩散系数随回流温度升高而增大。接头的剪切强度随回流时间延长先升后降,当回流时间为4 h时剪切强度最高;回流温度对剪切强度影响不大。

       

      Abstract: A 20 μm thick Sn-0.3Ag-0.7Cu solder paste was uniformly coated between two copper substrates. Transient liquid phase diffusion bonding tests were conducted at different reflow temperatures (240, 260, and 280 ℃) and different reflow time periods (0, 1, 2, 3, 4, and 8 h). The interfacial microstructure and shear property of the joints bonded by different processes were investigated. The results show that by reflow 240 ℃, the amount of Cu6Sn5 intermetallic compound at the joint interface increased and then decreased with the extension of reflow time period, and its morphology was transformed from a scalloped shape to a layered structure. When the reflow time was 4 h, the weld seam was almost filled with Cu6Sn5, and a thin Cu3Sn intermetallic compound layer was formed at interfaces between weld seam and base metal. After 8 h of reflow, large pores were formed in the weld seam, and the thickness of the Cu3Sn intermetallic compound layer increased. The thickness of the intermetallic compound layer first increased and then decreased with the extension of reflow time or increase of temperature. The growth of the intermetallic compound was characterized by volume diffusion, with the diffusion coefficient increasing at higher reflow temperatures. The shear strength of the joint first increased and then decreased with the extension of reflow time. When the reflow time was 4 h, the shear strength was the highest. The reflow temperature had little influence on the shear strength.

       

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