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    基于剪切稀化有机凝胶的磁流变液制备及其性能

    Magnetorheological Fluid Based on Shear-Thinning Organogel and Its Performances

    • 摘要: 在Span油凝胶中均匀掺入不同质量分数(1.0%~10.0%)亲水改性纳米SiO2颗粒,制备了具有明显剪切稀化特征的有机凝胶,通过流变性能测试确定了SiO2最佳添加量(质量分数)为5.0%;基于优化的有机凝胶制备了剪切稀化有机凝胶基磁流变液,研究了该磁流变液的性能。结果表明:剪切稀化有机凝胶基磁流变液在磁场作用下具有较高的屈服应力和剪切应力,仅在低剪切速率、高磁场强度条件下屈服应力略微降低,具有良好的磁响应性能。剪切稀化有机凝胶基磁流变液具有较宽的线型黏弹区,弹性特征显著;零场条件下剪切稀化有机凝胶基磁流变液的触变环面积大于Span油凝胶基磁流变液,说明掺入非磁性组分阻碍了磁致链束结构在磁场作用下的恢复能力。相较于矿物油基磁流变液,剪切稀化有机凝胶基磁流变液的响应时间略微延长,磁响应速率变慢。

       

      Abstract: Hydrophilic modified nano-SiO2 particles were homogeneously mixed into Span oleogel at different mass fractions (1.0%‒10.0%) to prepare shear-thinning organogel. The optimal SiO2 addition amount (mass fraction) was determined to be 5.0% by rheological tests. The shear-thinning organogel based magnetorheological fluid was fabricated using the optimized organogel and its properties were investigated.. The results show that the shear-thinning organogel based magnetorheological fluid had high yield stress and shear stress under magnetic fields, with only a slight decrease in yield stress observed under conditions of low shear rate and high magnetic field strength, indicating favorable magnetic responsiveness. The shear-thinning organogel based magnetorheological fluid exhibited a broad linear viscoelastic region, indicating that the notable elastic characteristics. Under zero-field conditions, the hysteresis loop area of the shear-thinning organogel based magnetorheological fluid was larger than that of the Span oilgel based magnetorheological fluid, suggesting that the incorporation of non-magnetic components impedes the recovery capability of the field-induced chain-like structures after the removal of the magnetic field. Compared with mineral oil based magnetorheological fluid, the shear-thinning organogel based magnetorheological fluid showed a slightly prolonged response time and a slower magnetic response rate.

       

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