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    铌酸钾钠基无铅压电陶瓷烧结助剂的研究进展

    Research Progress on Sintering Aids for (K, Na)NbO3 Based Lead-Free Piezoelectric Ceramics

    • 摘要: (K, Na)NbO3(KNN)基压电陶瓷是目前最具应用前景的无铅压电陶瓷体系,但是这类材料在高温烧结时由于碱金属离子挥发等原因而难以实现致密化。添加烧结助剂可以有效降低烧结温度,抑制碱金属离子的挥发,是提高KNN基无铅压电陶瓷致密性及压电性能的常用方法之一。简述了烧结助剂的工作机制,全面总结了目前KNN基无铅压电陶瓷中常用的烧结助剂及其作用机理,综述了各种烧结助剂对KNN基无铅压电陶瓷烧结特性、微观结构、压电特性等的影响,最后给出了KNN基无铅压电陶瓷烧结助剂今后的发展方向。

       

      Abstract: (K, Na)NbO3 (KNN) based piezoelectric ceramics are currently the most promising lead-free piezoelectric ceramic systems. However, these materials are difficult to achieve densification due to reasons such as the volatilization of alkali metal ions during sintering at high temperatures. Adding sintering aids can effectively lower the sintering temperature and inhibit the volatilization of alkali metal ions. It is one of the common methods to improve the compactness and piezoelectric properties of KNN based lead-free piezoelectric ceramics. The working mechanism of sintering aids is briefly described, and the commonly used sintering aids in KNN based lead-free piezoelectric ceramics at present and their action mechanisms are comprehensively summarized. The influence of various sintering aids on the sintering characteristics, microstructure, piezoelectric characteristics of KNN based lead-free piezoelectric ceramics is reviewed. Finally, the future development direction of sintering aids for KNN based lead-free piezoelectric ceramics is given.

       

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