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    不同铜含量Al-Si-Mg铸造合金的时效析出行为

    Aging Precipitation Behavior of Al-Si-Mg Cast Alloy with Different Copper Contents

    • 摘要: 铸造了不同铜质量分数(0,0.6%,1.2%,2.1%)的Al-Si-Mg-Cu合金,并进行双级固溶(500 ℃×6 h+530 ℃×4 h,水淬)+时效(175 ℃保温0~96 h,空冷)的T6热处理,研究了铜含量对合金时效析出行为的影响,分析了硬度“双峰”现象的形成机制。结果表明:铜质量分数不超过0.6%时合金硬度随时效时间延长先增大后减小,呈现单峰变化;铜质量分数不低于1.2%时合金出现硬度“双峰”现象,且第二个硬度峰值要略高于第一个。175 ℃下时效10 h后,低铜含量合金主要析出相为β″相,时效16 h后主要析出相不变;175 ℃下时效10 h后,高铜含量合金主要析出相为Q′相,时效16 h后主要析出相为θ′相。高铜含量合金硬度“双峰”现象是由时效过程中析出相演变引起的,主要析出相随时效时间延长由Q′相转变为θ′相。

       

      Abstract: Al-Si-Mg-Cu alloys with different copper mass fractions (0, 0.6%, 1.2%, 2.1%) were cast and subjected to T6 heat treatment of two-stage solid solution (500 ℃×6 h+530 ℃×4 h, water quenching) + aging (at 175 ℃ for 0−96 h, air cooling). The influence of copper content on the aging precipitation behavior of the alloy was studied. The formation mechanism of the "double peak" phenomenon in hardness was analyzed. The results show that the hardness of the alloy with a copper mass fraction not exceeding 0.6% first increased and then decreased with the extension of aging time, presenting a single-peak change. The alloy with a copper mass fraction of not less than 1.2% exhibited a "double peak" phenomenon in hardness, and the second hardness peak was slightly higher than the first one. After aging at 175 ℃ for 10 h, the main precipitated phase of the low-copper alloy was the β″ phase, and this remained unchanged after aging for 16 h. After aging at 175 ℃ for 10 h, the main precipitated phase of the high-copper alloy was the Q′ phase, and after aging for 16 h, the main precipitated phase changed to the θ′ phase. The "double peak" phenomenon of hardness of high copper content alloy was caused by the evolution of the types of precipitated phases during the aging process, and the main precipitated phase changed from Q′ phase to θ′ phase with the extension of aging time.

       

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