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    铸造Al-Si-Mg-xCu合金的时效析出行为

    Aging Precipitation Behavior of Cast Al-Si-Mg-xCu Alloy

    • 摘要: 铸造了不同铜质量分数(0,0.6%,1.2%,2.1%)的Al-Si-Mg-Cu合金,并进行双级固溶(500 ℃×6 h+530 ℃×4 h)+水淬+175 ℃时效0~96 h+空冷的T6热处理,研究了铜含量对合金时效析出行为的影响,分析了硬度“双峰”现象的形成机制。结果表明:低铜含量(不超过0.6%)合金硬度随时效时间延长先增大后减小,呈现单峰变化;高铜含量(超过0.6%)合金出现硬度“双峰”现象,且第二个硬度峰值要略高于第一个。175 ℃×10 h时效后,低铜含量合金主要析出相为β″相,高铜含量合金主要析出相为Q′相;175 ℃×16 h时效后,低铜含量合金主要析出相不变,高铜含量合金主要析出相为θ′相。高铜含量合金硬度“双峰”现象是由时效过程中析出相种类演变引起的,主要析出相随时效时间延长由Q′相转变为θ′相。

       

      Abstract: Al-Si-Mg-Cu alloys with different copper mass fractions (0, 0.6%, 1.2%, 2.1%) were cast and subjected to T6 heat treatment of two-stage solution treatment (500 ℃×6 h+530 ℃×4 h) + water quenching + aging at 175 ℃ for 0-96 h + air cooling. The influence of copper content on the aging precipitation behavior of the alloy was studied. The formation mechanism of the "double peak" phenomenon in hardness was analyzed. The results show that the hardness of the low copper content (not exceeding 0.6%) alloy first increased and then decreased with the extension of aging time, presenting a single-peak change. The high copper content (exceeding 0.6%) alloy exhibited a "double peak" phenomenon in hardness, and the second hardness peak was slightly higher than the first one. After aging at 175 ℃ for 10 h, the main precipitated phase of the low copper content alloy was the β″ phase, while that of the high copper content alloy was the Q′ phase. After aging at 175 ℃ for 16 h, the main precipitated phase of the low copper content alloy remained unchanged, while that of the high copper content alloy was the θ′ phase. The "double peak" phenomenon of hardness in high copper content alloys was caused by the evolution of the types of precipitated phases during the aging process, and the main precipitated phases changed from Q′ phase to θ′ phase as the aging time increased.

       

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