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    超声冲击对激光熔化沉积CrCoFeNi高熵合金组织和耐腐蚀性能的影响

    Effect of Ultrasonic Impact on Microstructure and Corrosion Resistance of CrCoFeNi High Entropy Alloy by Laser Melting Deposition

    • 摘要: 以气雾化等原子比CrCoFeNi预合金粉末为原料,采用激光熔化沉积技术制备CrCoFeNi高熵合金并进行超声冲击处理,研究了超声冲击对高熵合金物相组成、显微组织、显微硬度、残余应力及耐腐蚀性能的影响。结果表明:超声冲击处理后,高熵合金的物相仍为单一面心立方结构,表面形成塑性变形层,枝晶取向由垂直于合金表面变为近似平行于表面,表层形成超细晶、高密度位错及孪晶;超声冲击处理后合金表层显微硬度提高,在距表面0~500 μm区域残余应力发生拉-压转变,表面残余压应力最大,达230.8 MPa。超声冲击处理后,高熵合金的自腐蚀电位提高,自腐蚀电流密度减小,点蚀坑尺寸减小和数量减少且无应力腐蚀特征,耐腐蚀性能提升。

       

      Abstract: With gas atomized CrCoFeNi pre-alloyed powder with equal atomic ratio as raw materials, CrCoFeNi high entropy alloy was prepared by laser melting deposition, and was treated by ultrasonic impact technique. The effect of ultrasonic impact on the phase composition, microstructure, microhardness, residual stress and corrosion resistance of the high entropy alloy was investigated. The results show that after ultrasonic impact treatment, the high entropy alloy still had a single face centered cubic structure. After ultrasonic impact treatment, a plastic deformation layer formed on the surface, the orientation of dendrites changed from vertical to the alloy surface to approximately parallel to the surface, and the ultrafine grains, high-density dislocations and the twins formed on the surface. After ultrasonic impact treatment, the microhardness of the surface layer of alloy was improved the surface residual stress in the range of 0–500 µm from the alloy surface underwent a tensile-compression transition, and the surface residual compressive stress was the largest, reaching 230.8 MPa. After ultrasonic impact treatment, the self-corrosion potential of high entropy alloy increased, the self-corrosion current density decreased, the size and number of pitting corrosion pits decreased, and there was no stress corrosion characteristic; the corrosion resistance was improved.

       

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