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    镀铬30CrMnSiNi2A超高强度钢活塞杆在SO2盐雾环境中的腐蚀行为

    Corrosion Behavior of Chrome-Plated 30CrMnSiNi2A Ultra-High Strength Steel Piston Rod in SO2 Salt Spray Environment

    • 摘要: 通过质量分数3.5%NaCl溶液中的电化学测试、48 h SO2盐雾腐蚀试验及显微组织表征,研究了经金刚石工具光整与精磨抛光处理的镀铬30CrMnSiNi2A超高强度钢活塞杆的腐蚀行为。结果表明:铬镀层提高了活塞杆在NaCl介质中的耐腐蚀性能,表现为自腐蚀电位提高,自腐蚀电流密度下降。经48 h SO2盐雾腐蚀后,镀铬活塞杆表面发生明显腐蚀,主要为点蚀并伴随局部变色;点蚀区域附着红褐色腐蚀产物。点蚀源于铬镀层在SO2盐雾环境中先发生腐蚀,暴露出铬镀层的固有微裂纹,腐蚀介质通过微裂纹渗透后,铬镀层与暴露的钢基体构成大阴极-小阳极腐蚀电偶,加速了钢基体腐蚀,形成点蚀坑并造成铬镀层起裂。局部变色源于镀层表面轻微腐蚀后变得粗糙。镀层中的微裂纹是导致钢基体发生腐蚀的主要原因。

       

      Abstract: The corrosion behavior of a chromium-plated 30CrMnSiNi2A ultra-high strength steel piston rod treated with diamond tool finishing and fine polishing was studied by electrochemical test in a NaCl solution with 3.5% mass fraction, 48 h SO2 salt spray corrosion test, and microstructural characterization. The results show that chromium plating improved the corrosion resistance of the piston rod in NaCl medium, which was manifested as the increase in the self-corrosion potential and the decrease in the self-corrosion current density. After 48 h of SO2 salt spray corrosion, obvious corrosion was observed on the surface of the chromium-plated piston rod, mainly manifested as pitting accompanied by localized discoloration; reddish-brown corrosion products adhered to the pitting areas. The pitting corrosion originated from the initial corrosion of the chromium plating in the SO2 salt spray environment, exposing the inherent microcracks of the chromium plating. After the corrosive medium penetrated through these microcracks, the chromium plating and the exposed steel matrix formed a large cathode-small anode corrosion couple, which accelerated the corrosion of the steel matrix, resulting in the formation of pitting pits and causing the crack of chromium plating. The localized discoloration was attributed to the roughening of the coating surface due to slight corrosion. The microcracks in the plating were identified as the main cause of corrosion of the steel matrix.

       

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