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    王晓虹, 任耀剑, 冯培忠. MoSi2发热元件表面保护膜的形貌与结构[J]. 机械工程材料, 2008, 32(1): 63-66.
    引用本文: 王晓虹, 任耀剑, 冯培忠. MoSi2发热元件表面保护膜的形貌与结构[J]. 机械工程材料, 2008, 32(1): 63-66.
    WANG Xiao-hong, REN Yao-jian, FENG Pei-zhong. Scale of MoSi2 Heating Element[J]. Materials and Mechanical Engineering, 2008, 32(1): 63-66.
    Citation: WANG Xiao-hong, REN Yao-jian, FENG Pei-zhong. Scale of MoSi2 Heating Element[J]. Materials and Mechanical Engineering, 2008, 32(1): 63-66.

    MoSi2发热元件表面保护膜的形貌与结构

    Scale of MoSi2 Heating Element

    • 摘要: 采用SEM和EDS技术研究了国外某MoSi2发热元件表面保护膜的成分和微观组织.结果表明:在MoSi2发热元件外表面存在一层光滑致密的厚度超过10 μm的玻璃保护膜,膜和基体之间界面清晰,结合紧密,该膜是一种以SiO2为主,含有少量铝、钠、镁和钙氧化物的复合成分的玻璃保护膜;在最外层玻璃保护膜和基体之间存在1~2 μm厚的Mo5Si3过渡层;复合成分玻璃保护膜和Mo5Si3过渡层的出现有利于调整保护膜和基体之间热膨胀系数的差异,提高保护膜和基体结合的稳定性,有利于发热元件的高温使用.

       

      Abstract: The content and microstructure of scale of Kanthal Super 1700 MoSi2 heating element were studied using scanning electron microscope (SEM) with energy dispersive spectrometer (EDS).A homogeneous and smooth glass scale more than 10 μm in thickness was observed.The interface between scale and matrix was very clear and excellent bond was formed.This scale was composite glass with high content SiO2 and less oxides of Al,Na,Mg and Ca.A layer of Mo5Si3 with 1-2 μm in thickness was observed between glass scale and matrix.That composite glass scale and Mo5Si3 substrate would be beneficial to adjust the difference of coefficient of thermal expansion between scale and matrix.They can also improve the bonding stability of scale and matrix.This is good for the application of MoSi2 heating element.

       

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