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    王荣, 董昭, 雒设计, 许天旱. J55碳钢在不同流速NaCl溶液中的腐蚀行为[J]. 机械工程材料, 2015, 39(4): 29-34.
    引用本文: 王荣, 董昭, 雒设计, 许天旱. J55碳钢在不同流速NaCl溶液中的腐蚀行为[J]. 机械工程材料, 2015, 39(4): 29-34.
    WANG Rong, DONG Zhao, LUO She-ji, XU Tian-han. Corrosion Behavior of J55 Carbon Steel in NaCl Solution at Different Flow Velocities[J]. Materials and Mechanical Engineering, 2015, 39(4): 29-34.
    Citation: WANG Rong, DONG Zhao, LUO She-ji, XU Tian-han. Corrosion Behavior of J55 Carbon Steel in NaCl Solution at Different Flow Velocities[J]. Materials and Mechanical Engineering, 2015, 39(4): 29-34.

    J55碳钢在不同流速NaCl溶液中的腐蚀行为

    Corrosion Behavior of J55 Carbon Steel in NaCl Solution at Different Flow Velocities

    • 摘要: 采用电化学测试和浸泡试验研究了J55碳钢在不同流速质量分数为3.5% NaCl溶液中的腐蚀行为, 分析了流动速率(0,0.5,1 m·s-1)对其腐蚀行为的影响及相关机理。结果表明: NaCl溶液流动使该钢的开路电位和自腐蚀电位正移, 自腐蚀电流密度增加, 双电层的极化电阻降低; 溶液流动对阳极溶解的机制没有明显的影响, 但提高了阴极反应的Tafel斜率; 在流速为1 m·s-1的溶液中, J55碳钢的平均腐蚀速率比在静止溶液中的显著增大, 并促进了局部腐蚀的发生; 溶液流动促进了阴极离子的传递过程, 减小了腐蚀产物膜的电阻。

       

      Abstract: The corrosion behavior of J55 carbon steel in 3.5wt% NaCl solution with different flow velocities was investigated by means of electrochemical measurements and immersion tests. The mechanism and the effect of solution flow velocity on corrosion of J55 carbon steel were analyzed. The results show that NaCl solution flow made open circuit potential and self-corrosion potential shift toward positive, self-corrosion current density increase and polarization resistance of double layer decrease. Flow of solution had little effect on the mechanism of the anodic reaction in the corrosion process, but increased the value of Tafel slope for the cathodic reaction. The average corrosion rate of J55 steel in the solution with flow velocity of 1 mm·s-1 was higher than in the stagnant solution and the flow enhanced the occurrence of localized corrosion. Solution flow promoted cathode ion transfer and demoted the resistance of corrosion product.

       

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