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    钛含量对低镍铜合金显微组织和性能的影响

    Influence of Ti Content on Microstructure and Properties of Low-Nickel Copper Alloys

    • 摘要: 采用真空感应熔炼法制备了不同钛含量的Cu-2.8Ni-1.1Fe-0.9Mn-xTi (x=0~1.79%, 质量分数) 低镍铜合金, 采用显微组织观察、拉伸试验和腐蚀试验等研究了钛含量对合金显微组织、力学性能及在模拟海水中耐腐蚀性能的影响。结果表明: 低镍铜合金中加入少量钛后, 晶粒明显细化, 组织中有细小弥散分布的第二相析出, 并随钛含量的增加而增多, 当合金中钛含量为1.79%时, 组织中还出现了大尺寸块状相; 随着钛含量的增加, 低镍铜合金的强度和硬度逐渐提高, 而塑性则有一定下降; 在模拟海水中加钛铜合金的腐蚀速率随钛含量的增加先降后升, 且均小于不加钛的铜合金, 钛含量为0.88%时, 腐蚀速率最低, 为14.486 6 mg·m-2·h-1。

       

      Abstract: Cu-2.8Ni-1.1Fe-0.9Mn-xTi low-nickel copper alloys with different contents of Ti (x=0~1.79%, mass) were prepared by vacuum induction melting. The effects of Ti content on microstructure, mechanical properties and corrosion resistance in simulated seawater of the copper alloy were studied by microstructure observation, tensile testing and corrosion testing. The results show that the grain size decreased obviously, and the small and dispersed phases precipitated with adding element Ti in the low-nickel copper alloy; the precipitation phases increased with increasing the Ti content; besides the small and dispersed phases, massive phases appeared in the copper alloy with 1.79% Ti added. The tensile strength and hardness of the low-nickel copper alloy improved gradually and the plasticity slightly decreased with the increase of Ti content. The corrosion rates of the copper alloys with Ti in simulated seawater first decreased and then increased with the increase of Ti content, but all of them were lower than that of the copper alloy without Ti. The copper alloy with 0.88% Ti has the lowest corrosion rate, 14.486 6 mg·m-2·h-1.

       

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