高级检索
    王东生, 黄因慧, 田宗军, 刘志东, 朱军. 脉冲喷射电沉积纳米镍涂层的组织与耐腐蚀性能[J]. 机械工程材料, 2008, 32(2): 53-56.
    引用本文: 王东生, 黄因慧, 田宗军, 刘志东, 朱军. 脉冲喷射电沉积纳米镍涂层的组织与耐腐蚀性能[J]. 机械工程材料, 2008, 32(2): 53-56.
    WANG Dong-sheng, HUANG Yin-hui, TIAN Zong-jun, LIU Zhi-dong, ZHU Jun. Microstructure and Corrosion Resistance of Nanocrystalline Nickel Coatings Prepared by Pulse Jet Electrodepositing[J]. Materials and Mechanical Engineering, 2008, 32(2): 53-56.
    Citation: WANG Dong-sheng, HUANG Yin-hui, TIAN Zong-jun, LIU Zhi-dong, ZHU Jun. Microstructure and Corrosion Resistance of Nanocrystalline Nickel Coatings Prepared by Pulse Jet Electrodepositing[J]. Materials and Mechanical Engineering, 2008, 32(2): 53-56.

    脉冲喷射电沉积纳米镍涂层的组织与耐腐蚀性能

    Microstructure and Corrosion Resistance of Nanocrystalline Nickel Coatings Prepared by Pulse Jet Electrodepositing

    • 摘要: 采用脉冲喷射电沉积方法在45钢基体表面制备了纳米镍涂层,用扫描电镜和X射线衍射仪研究了平均电流密度对镍涂层表面形貌、微观组织结构及平均晶粒尺寸的影响,并进行了耐腐蚀性试验.结果表明:用该方法制备的纳米镍涂层表面比较平整、晶粒细小并且结合较致密,但晶粒间仍存在一定的孔隙;随着平均电流密度的增大,平均晶粒尺寸先变小再变大,当平均电流密度为39.8 A·dm-2时涂层最致密,平均晶粒尺寸最小(13.7 nm);纳米镍涂层试样的耐腐蚀性能有较大的提高,但经过一段时间后腐蚀速率有所上升,这可能与腐蚀介质的渗入有很大关系.

       

      Abstract: Nanocrystalline nickel coatings were prepared by pulse jet electrodepositing on the substrate of 45 carbon steel.The effects of average current densities on the surface morphology,microstructure and average grain sizes of nickel coatings were studied by SEM and XRD,and the corrosion resistance was also tested.The results show that the nickel coatings prepared by pulse jet electrodepositing have smooth surfaces,fine grain sizes and good compact quality.However,there are still some pores between grains.With the increase of average current densities,average grain sizes of nickel coatings become finer and then bigger.Using optimum process parameter of average current density of 39.8 A·dm-2,a coating with the best compact quality and finest average grain sizes (13.7 nm) is obtained.After pulse jet electrodeposition,the corrosion resistance is obviously increased,but after some time the corrosion rate increase,which might be greatly related to the infiltration of corrosive media.

       

    /

    返回文章
    返回