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    游小刚, 谭毅, 李佳艳. 采用原位反应法在石墨坩埚表面制备SiC涂层[J]. 机械工程材料, 2014, 38(6): 50-55.
    引用本文: 游小刚, 谭毅, 李佳艳. 采用原位反应法在石墨坩埚表面制备SiC涂层[J]. 机械工程材料, 2014, 38(6): 50-55.
    YOU Xiao-gang, TAN Yi, LI Jia-yan. Preparation of SiC Coatings on Graphite Crucible by In-situ Reaction Method[J]. Materials and Mechanical Engineering, 2014, 38(6): 50-55.
    Citation: YOU Xiao-gang, TAN Yi, LI Jia-yan. Preparation of SiC Coatings on Graphite Crucible by In-situ Reaction Method[J]. Materials and Mechanical Engineering, 2014, 38(6): 50-55.

    采用原位反应法在石墨坩埚表面制备SiC涂层

    Preparation of SiC Coatings on Graphite Crucible by In-situ Reaction Method

    • 摘要: 通过原位反应在石墨坩埚切片表面成功制备了SiC涂层, 并对其进行了循环热氧化试验, 研究了SiC涂层的形成机理以及烧结温度和时间对涂层厚度的影响, 并评价了涂层对提高石墨抗热氧化性及抗热冲击性的作用。结果表明: 原位反应制备的SiC涂层厚度较为均匀; 不同温度下的原位反应由不同的动力学过程控制; 当温度接近硅熔点时, 长时间加热能显著增加SiC涂层的厚度; 烧结温度越高, SiC涂层的厚度越大; 石墨表面的SiC涂层能够提高石墨基体的抗热氧化及抗热冲击性, 且涂层厚度越大, 作用越显著。

       

      Abstract: SiC coatings were prepared successfully on graphite crucible slices surface by in-situ reaction method and cyclic thermal oxidation experiments of the coatings were performed . The formation mechanism of SiC coating and the effects of sintering temperature and time on the thickness of the coatings were studied, and the roles of the coating in improving thermal oxidation resistance and thermal shock resistance were also evaluated. The results show that the thickness of SiC coatings prepared by in-situ reaction method was uniform. The in-situ reactions at different temperatures were controlled by different kinetic processes. When the temperature was very close to the melting point of silicon, long heating time could significantly increase the thickness of SiC coatings, and the higher the sintering temperature, the larger the thickness of the coating. SiC coatings on graphite surface could greatly improve the thermal oxidation resistance and thermal shock resistance of the graphite matrix, and the improvement was more significant with the greater coating thickness.

       

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