• 中文核心期刊
  • CSCD中国科学引文数据库来源期刊
  • 中国科技核心期刊
  • 中国机械工程学会材料分会会刊
Advanced Search
WANG Yunqiang, LEI Weining, SHEN Yu, QIAN Haifeng, LI Qilin, LI Xiaoping. Effect of Graphene Oxide Mass Concentration on Properties of Nickel-based Graphene Composite Electroforming Layer under Supercritical Condition[J]. Materials and Mechanical Engineering, 2017, 41(8): 12-17. DOI: 10.11973/jxgccl201708003
Citation: WANG Yunqiang, LEI Weining, SHEN Yu, QIAN Haifeng, LI Qilin, LI Xiaoping. Effect of Graphene Oxide Mass Concentration on Properties of Nickel-based Graphene Composite Electroforming Layer under Supercritical Condition[J]. Materials and Mechanical Engineering, 2017, 41(8): 12-17. DOI: 10.11973/jxgccl201708003

Effect of Graphene Oxide Mass Concentration on Properties of Nickel-based Graphene Composite Electroforming Layer under Supercritical Condition

More Information
  • Received Date: July 28, 2016
  • Revised Date: June 24, 2017
  • A nickel-based graphene composite electroforming layer was prepared under supercritical and ordinary conditions, respectively. The effects of two preparation conditions and graphene oxide (GO) mass concentration on the microstructure, surface morphology, hardness and wear resistance of the composite electroforming layer were investigated. The results show that comparing to those under the ordinary condition, the microstructure of the composite electroforming layer under the supercritical condition was compact and the surface roughness was lower; the preferred degree of the Ni crystal face (111) and (220) decreased while that of the crystal face (220) increased; the hardness and wear resistance were improved. Under the supercritical condition, with the increase of the GO mass concentration, the microhardness, wear resistance and the embedding amount of graphene nanosheets all first increased then decreased. When the GO mass concentration was 0.20 g·L-1, the graphene content in the composite electroforming layer was the highest, and the microhardness reached the largest value of 768 HV, also the relative wear resistance was the best.
  • [1]
    YAN T, LI L, WANG L. A simple nickel activation process for electroless nickel-phosphorus plating on carbon fiber[J]. BioResources, 2012, 8(1):340-349.
    [2]
    王元刚, 宁智, 吴蒙华. 电流密度对氨基磺酸盐镀液电沉积纳米TiN/Ni复合镀层性能的影响[J]. 机械工程材料, 2016, 40(2):47-50.
    [3]
    朱增伟, 朱荻. 硬质粒子摩擦法电铸新技术的研究[J]. 中国机械工程, 2006, 17(1):60-63.
    [4]
    VASIL'EVA E A, TSURKAN A V, PROTSENKO V S, et al. Electrodeposition of composite Fe-TiO2 coatings from methanesulfonate electrolyte[J]. Protection of Metals and Physical Chemistry of Surfaces, 2016, 52(3):532-537.
    [5]
    JIA F, DUAN N, WU S, et al. Impedimetric salmonella, aptasensor using a glassy carbon electrode modified with an electrodeposited composite consisting of reduced graphene oxide and carbon nanotubes[J]. Microchimica Acta, 2015, 183(1):337-344.
    [6]
    QIAN H F, LEI W N, WANG C Y,et al. Microstructure and microhardness studies of nickel-based diamond composite coatings by electrodepositing in supercritical CO2[J]. Materials Research Innovations,2015,19(s10):1-4.
    [7]
    刘维桥, 雷卫宁, 曲宁松,等. 基于SCF-CO2电沉积制备纳米材料的研究进展[J]. 稀有金属材料与工程, 2010, 39(11):2064-2068.
    [8]
    SHIMIZU T, ISHIMOTO Y, CHANG T F M, et al. Cu wiring into nano-scale holes by electrodeposition in supercritical carbon dioxide emulsified electrolyte with a continuous-flow reaction system[J]. The Journal of Supercritical Fluids, 2014, 90:60-64.
    [9]
    WANG W, WANG Y, GAO Y, et al. Control of number of graphene layers using ultrasound in supercritical CO2, and their application in lithium-ion batteries[J]. The Journal of Supercritical Fluids, 2014, 85:95-101.
    [10]
    WANG J K, CHAR J M. An optimization study on electrodeposition of copper from acid bath with supercritical carbon dioxide fluid[J]. Journal of Chemistry and Chemical Engineering, 2012, 6(10):878-884.
    [11]
    CHUNG S T, TSAI W T. Nanocrystalline Ni-C electrodeposits prepared in electrolytes containing supercritical carbon dioxide[J]. Journal of the Electrochemical Society, 2009, 156(11):D457-D461.
    [12]
    QI X, PU K Y, LI H,et al. Amphiphilic graphene composites[J]. Angewandte Chemie International Edition, 2010, 49(49):9426-9429.
    [13]
    KUMAR M K P, SRIVASTAVA C. Synthesis of graphene from a used battery electrode[J].JOM,2016,68(1):374-383.
    [14]
    沈宇.超临界状态下石墨烯复合电铸工艺研究[D].常州:江苏理工学院,2016:1-10.
    [15]
    LIU W Q, LEI W N, WANG C Y, et al. Ni-SiC nanocomposites electroplating process under ultrasonic and agitation[J].Integrated Ferroelectrics,2015,167(1):192-198.
    [16]
    许书楷,杨防祖,周绍民.电沉积条件对锌镀层织构的影响[J].电化学,1995,1(4):408-414.

Catalog

    Article views (3) PDF downloads (0) Cited by()

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return