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ZENG Bin, LIU Wanfeng, ZENG Wujun. Preparation and Photocatalytic Properties of Ordered Mesoporous ZnS Nanorods Loading on Graphene Composite[J]. Materials and Mechanical Engineering, 2018, 42(9): 41-46. DOI: 10.11973/jxgccl201809009
Citation: ZENG Bin, LIU Wanfeng, ZENG Wujun. Preparation and Photocatalytic Properties of Ordered Mesoporous ZnS Nanorods Loading on Graphene Composite[J]. Materials and Mechanical Engineering, 2018, 42(9): 41-46. DOI: 10.11973/jxgccl201809009

Preparation and Photocatalytic Properties of Ordered Mesoporous ZnS Nanorods Loading on Graphene Composite

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  • Received Date: June 09, 2017
  • Revised Date: July 18, 2018
  • The composite of ordered mesoporous ZnS nanorods loading on graphene was prepared by microwave-assisted heating. The microscopic morphology and phase composition of the composite were studied; the effect of graphene oxide content (0-15wt%) and microwave heating power (320-800 W) and time (0-80 min) on microscopic morphology and photocatalytic performance was analyzed; the formation mechanism of the composite, and the relation between micromorphology and photocatalytic performance were discussed. The results show that the composite consisted of flake graphene and rodlike ZnS, and ordered mesoporus ZnS nanorods distributed on the surface of graphene evenly. The increase of graphene oxide content was favorable for dispersion of ZnS nanorods. The formation of ZnS nanorods was promoted with the increase of microwave heating power and time. The photocatalytic performance of the composite was the best when the microwave heating time was 60 min, microwave heating power was 640 W, and the content of graphene oxide was 10wt%.
  • [1]
    AN X Q, YU X L, YU J C, et al. CdS nanorods/reduced graphene oxide nanocomposites for photocatalysis and electrochemical sensing[J]. Journal of Materials Chemistry A, 2013,1(16):5158-5164.
    [2]
    XIANG Q J, YU J G, JARONIEC M. Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles[J]. Journal of the American chemical society, 2012, 134(15):6575-6578.
    [3]
    ZHANG J Y, WANG Y G, ZHANG J, et al. Enhanced photocatalytic hydrogen production activities of Au loaded ZnS flowers[J]. Applied Materials & Interfaces, 2013, 5(3):1031-1037.
    [4]
    ZHANG J, YU J G, ZHANG Y M, et al. Visible light photocatalytic H2-production activity of CuS/ZnS porous nanosheets based on photoinduced interfacial charge transfer[J]. Nano Letters, 2011,11(11):4774-4779.
    [5]
    ZENG B, LONG H. ZnS nanoflowers on graphene for use as a high-performance photocatalyst[J]. Nano, 2014,9(8):1450097.
    [6]
    WANG C, AO Y H, WANG P F, et al. A simple method for large-scale preparation of ZnS nanoribbon film and its photocatalytic activity for dye degradation[J]. Applied Surface Science, 2010, 256(13):4125-4128.
    [7]
    ZENG B, CHEN X H, TANG Q X, et al. Ordered mesoporous necklace-like ZnS on graphene for use as a high performance photocatalyst[J]. Applied Surface Science, 2014, 308(8):321-327.
    [8]
    ZHANG G Y, FENG Y, XU Y Y, et al. Controlled synthesis of mesoporous α-Fe2O3 nanorods and visible light photocatalytic property[J]. Materials Research Bulletin, 2012, 47(3):625-630.
    [9]
    JIANG H, DAI H, MENG X, et al. Porous olive-like BiVO4:Alcoho-hydrothermal preparation and excellent visible-light-driven photocatalytic performance for the degradation of phenol[J].Applied Catalysis B:Environmental, 2011,105(3/4):326-334.
    [10]
    ZHANG L, AN L, LIU B, et al. Synthesis and photocatalytic activity of porous polycrystalline NiO nanowires[J]. Applied Physics A, 2011,104(1):69-75.
    [11]
    SHAMI Z, NASER S. A well-designed three-dimensional ternary hierarchical co-axial ZnO@ZnS heteroarchitecture decorated electrospun carbon hollow tube nanofibrous mat:Improved ultraviolet-light photocatalytic performance[J]. CrystEngComm, 2016,16(5):910-921.
    [12]
    FENG S A, ZHAO J H, ZHU Z P. The manufacture of carbon nanotubes decorated with ZnS to enhance the ZnS photocatalytic activity[J]. New Carbon Materials, 2008,23(3):228-234.
    [13]
    HU H T, WANG X B, LIU F M, et al. Rapid microwave-assisted synthesis of graphene nanosheets-zinc sulfide nanocomposites:Optical and photocatalytic properties[J]. Synthetic Metals, 2011,161(5/6):404-410.
    [14]
    XIANG Q J, LANG D, SHEN T T, et al. Graphene-modified nanosized Ag3PO4 photocatalysts for enhanced visible-light photocatalytic activity and stability[J]. Applied Catalysis B:Environmental, 2015,162:196-203.
    [15]
    ZENG B, CHEN X H, CHEN C S, et al. Reduced graphene oxides loaded-ZnS/CuS heteronanostructures as high-activity visible-light-driven photocatalysts[J]. Journal of Alloys & Compounds, 2014,582(1):774-779.
    [16]
    CHEN J, YAO B W, LI C, et al. An improved Hummers method for eco-friendly synthesis of graphene oxide[J]. Carbon, 2013,64(11):225-229.
    [17]
    LIU Y, HU J C, ZHOU T F, et al. Self-assembly of layered wurtzite ZnS nanorods/nanowires as highly efficient photocatalysts[J]. Journal of Materials Chemistry, 2011,21(41):16621-16627.

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