Corrosion Behavior of Oil Casing Steel under Combustion Drive Oil Condition at Different Temperatures
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Abstract
The corrosion behavior of oil casing steels N80, BG80-3Cr, P110, BG90H, BG90H-9Cr and BG90H-13Cr at different temperatures was investigated under simulated combustion drive oil condition, and the corrosion mechanism was analyzed. The results show that at a relatively low temperature (50℃), oxygen and CO2 corrosion mainly occurred in the tested steels. The corrosion product was FeCO3 and had poor protection poerformance. Therefore the average corrosion rate was relatively high. At a relatively high temperature (150℃), oxygen corrosion gradually took the dominant role. The corrosion products consisted of Fe3O4 and FeCO3, whose protection performance decreased, and the average corrosion rate increased. At a high temperature (250℃), the corrosion mechanism was oxygen corrosion. The corrosion product was Fe3O4. The Fe3O4 hydrate film had high protection performance, and uniform corrosion rate decreased. The average corrosion rates of N80 steel, BG80-3Cr steel, P110 steel, BG90H steel were significantly higher than those of BG90H-9Cr steel and BG90H-13Cr steel, and were all higher than 0.2 mm·a-1 at 50,150℃. The average corrosion rates of BG90H-9Cr steel and BG90H-13Cr steel were both lower than 0.2 mm·a-1, indicating good corrosion resistance under combustion drive oil condition.
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