• 中文核心期刊
  • CSCD中国科学引文数据库来源期刊
  • 中国科技核心期刊
  • 中国机械工程学会材料分会会刊
Advanced Search
PAN Xincheng, LIN Zhengqi, YANG Liu, DENG Liping. Research Progress on Preparation Process and Properties of Graphene Reinforced Copper Matrix Composites[J]. Materials and Mechanical Engineering, 2023, 47(1): 1-10. DOI: 10.11973/jxgccl202301001
Citation: PAN Xincheng, LIN Zhengqi, YANG Liu, DENG Liping. Research Progress on Preparation Process and Properties of Graphene Reinforced Copper Matrix Composites[J]. Materials and Mechanical Engineering, 2023, 47(1): 1-10. DOI: 10.11973/jxgccl202301001
shu

Research Progress on Preparation Process and Properties of Graphene Reinforced Copper Matrix Composites

  • School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou 350108, China

More Information
  • Received Date: September 19, 2021
  • Revised Date: November 08, 2022
    Graphical Abstract
    • Abstract
  • As a commonly used metal material, copper is limited in its application due to its low strength. Because of its excellent comprehensive properties, graphene has attracted wide attention as a potential reinforcement. Graphene reinforced copper matrix composites combine the great properties of both copper and graphene, and have become an research hotspot. The preparation processes and comprehensive properties of graphene reinforced copper matrix composites are introduced. The characteristics of various preparation processes, strengthening mechanism and configuration design are emphatically discussed, and the improvement approaches to solve the two main technical difficulties of weak bonding of composite interface and difficult dispersion of graphene are summarized. Finally, the preparation process of graphene reinforced copper matrix composites is prospected.
    • FullText(HTML)
    • References (71)
  • [1]
    李周, 肖柱, 姜雁斌, 等.高强导电铜合金的成分设计、相变与制备[J].中国有色金属学报, 2019, 29(9):2009-2049.

    LI Z, XIAO Z, JIANG Y B, et al.Composition design, phase transition and fabrication of copper alloys with high strength and electrical conductivity[J].The Chinese Journal of Nonferrous Metals, 2019, 29(9):2009-2049.
    [2]
    吴德振, 杨为良, 徐恒雷, 等.高强高导铜合金的应用与制备方法[J].热加工工艺, 2019, 48(4):19-25.

    WU D Z, YANG W L, XU H L, et al.Application and preparation methods of high strength and high conductivity Cu alloy[J].Hot Working Technology, 2019, 48(4):19-25.
    [3]
    刘志锋, 邓丽萍, 沈莉香.高强度高导电铜基复合材料的研究进展[J].热加工工艺, 2019, 48(8):14-18.

    LIU Z F, DENG L P, SHEN L X.Research progress of high-strength and high-conductivity copper-based materials[J].Hot Working Technology, 2019, 48(8):14-18.
    [4]
    NOVOSELOV K S, GEIM A K, MOROZOV S V, et al.Electric field effect in atomically thin carbon films[J].Science, 2004, 306(5696):666-669.
    [5]
    LEE C G, WEI X D, KYSAR J W, et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science, 2008, 321(5887):385-388.
    [6]
    BALANDIN A A, GHOSH S, BAO W Z, et al.Superior thermal conductivity of single-layer graphene[J].Nano Letters, 2008, 8(3):902-907.
    [7]
    李秀辉, 燕绍九, 洪起虎, 等.石墨烯添加量对铜基复合材料性能的影响[J].材料工程, 2019, 47(1):11-17.

    LI X H, YAN S J, HONG Q H, et al.Influence of graphene content on properties of Cu matrix composites[J].Journal of Materials Engineering, 2019, 47(1):11-17.
    [8]
    SALVO C, MANGALARAJA R V, UDAYABASHKAR R, et al.Enhanced mechanical and electrical properties of novel graphene reinforced copper matrix composites[J].Journal of Alloys and Compounds, 2019, 777:309-316.
    [9]
    WANG P, LIU W, CHEN L, et al.Bio-inspired laminated graphite nanosheets/copper composites[J].RSC Advances, 2015, 5(63):51342-51346.
    [10]
    ZHANG D D, ZHAN Z J.Experimental investigation of interfaces in graphene materials/copper composites from a new perspective[J].RSC Advances, 2016, 6(57):52219-52226.
    [11]
    WANG L D, CUI Y, LI B, et al.High apparent strengthening efficiency for reduced graphene oxide in copper matrix composites produced by molecule-lever mixing and high-shear mixing[J].RSC Advances, 2015, 5(63):51193-51200.
    [12]
    YANG Z Y, WANG L D, SHI Z D, et al.Preparation mechanism of hierarchical layered structure of graphene/copper composite with ultrahigh tensile strength[J].Carbon, 2018, 127:329-339.
    [13]
    WANG S Y, HAN S B, XIN G Q, et al.High-quality graphene directly grown on Cu nanoparticles for Cu-graphene nanocomposites[J].Materials & Design, 2018, 139:181-187.
    [14]
    LI X H, YAN S J, CHEN X, et al.Microstructure and mechanical properties of graphene-reinforced copper matrix composites prepared by in situ CVD, ball-milling, and spark plasma sintering[J].Journal of Alloys and Compounds, 2020, 834:155182.
    [15]
    ZHAO X Y, TANG J C, YU F X, et al.Preparation of graphene nanoplatelets reinforcing copper matrix composites by electrochemical deposition[J].Journal of Alloys and Compounds, 2018, 766:266-273.
    [16]
    SONG G S, WANG Q, SUN L, et al.One-step synthesis of sandwich-type Cu/graphene/Cu ultrathin foil with enhanced property via electrochemical route[J].Materials & Design, 2020, 191:108629.
    [17]
    ZHANG X, WAN D Q, PENG K, et al.Enhancement of thermal conductivity and mechanical properties of Cu-reduced graphene oxide composites by interface modification[J].Journal of Materials Engineering and Performance, 2019, 28(8):5165-5171.
    [18]
    SHAO G S, LIU P, ZHANG K, et al.Mechanical properties of graphene nanoplates reinforced copper matrix composites prepared by electrostatic self-assembly and spark plasma sintering[J].Materials Science and Engineering:A, 2019, 739:329-334.
    [19]
    CHEN F, MEI Q S, LI J Y, et al.Fabrication of graphene/copper nanocomposites via in situ delamination of graphite in copper by accumulative roll-compositing[J].Composites Part B:Engineering, 2021, 216:108850.
    [20]
    KIM W J, LEE T J, HAN S H.Multi-layer graphene/copper composites:Preparation using high-ratio differential speed rolling, microstructure and mechanical properties[J].Carbon, 2014, 69:55-65.
    [21]
    KORZNIKOVA G, CZEPPE T, KHALIKOVA G, et al.Microstructure and mechanical properties of Cu-graphene composites produced by two high pressure torsion procedures[J].Materials Characterization, 2020, 161:110122.
    [22]
    SINGH D, DAS A, MALLIK A.Corrosion behaviour of electrophoretic deposited graphene on copper[J].Materials Today:Proceedings, 2019, 15:A1-A8.
    [23]
    NAIK R B, REDDY K V, REDDY G M, et al.Development of high strength and high electrical conductivity Cu/Gr composites through friction stir processing[J].Materials Letters, 2020, 265:127437.
    [24]
    CHOI J, OKIMURA N, YAMADA T, et al.Deposition of graphene-copper composite film by cold spray from particles with graphene grown on copper particles[J].Diamond and Related Materials, 2021, 116:108384.
    [25]
    管振宏, 于镇洋, 乔志军, 等.化学气相沉积法制备原位生长三维石墨烯/铜基复合材料[J] .材料科学与工程学报, 2021, 39(4):575-579.

    GUAN Z H, YU Z Y, QIAO Z J, et al.Preparation of in-situ growth three-dimensional Cu@graphene composite by chemical vapor deposition[J].Journal of Materials Science & Engineering, 2021, 39(4):575-579.
    [26]
    ZHU J D, LIU X, ZHOU X H, et al.Strengthening effect of graphene-edge dislocation interaction in graphene reinforced copper matrix composites[J].Computational Materials Science, 2021, 188:110179.
    [27]
    KIM Y, LEE J, YEOM M S, et al.Strengthening effect of single-atomic-layer graphene in metal-graphene nanolayered composites[J].Nature Communications, 2013, 4:2114.
    [28]
    ZHANG D D, XIAO H X, JIANG W, et al.Effect of graphene lateral size on the microstructure and properties of graphene/copper composites[J].International Journal of Modern Physics B, 2020, 34:2040045.
    [29]
    LI Z, FU X D, GUO Q, et al.Graphene quality dominated interface deformation behavior of graphene-metal composite:The defective is better[J].International Journal of Plasticity, 2018, 111:253-265.
    [30]
    CAO M, XIONG D B, TAN Z Q, et al.Aligning graphene in bulk copper:Nacre-inspired nanolaminated architecture coupled with in situ processing for enhanced mechanical properties and high electrical conductivity[J].Carbon, 2017, 117:65-74.
    [31]
    ZHANG X, SHI C S, LIU E Z, et al.Achieving high strength and high ductility in metal matrix composites reinforced with a discontinuous three-dimensional graphene-like network[J].Nanoscale, 2017, 9(33):11929-11938.
    [32]
    WANG J, GUO L N, LIN W M, et al.The effects of graphene content on the corrosion resistance, and electrical, thermal and mechanical properties of graphene/copper composites[J].New Carbon Materials, 2019, 34(2):161-169.
    [33]
    TANG Y X, YANG X M, WANG R R, et al.Enhancement of the mechanical properties of graphene-copper composites with graphene-nickel hybrids[J].Materials Science and Engineering:A, 2014, 599:247-254.
    [34]
    YOO S C, LEE J, HONG S H.Synergistic outstanding strengthening behavior of graphene/copper nanocomposites[J].Composites Part B:Engineering, 2019, 176:107235.
    [35]
    ZHANG D D, ZHAN Z J.Strengthening effect of graphene derivatives in copper matrix composites[J].Journal of Alloys and Compounds, 2016, 654:226-233.
    [36]
    XIANG S L, WANG X J, GUPTA M, et al.Graphene nanoplatelets induced heterogeneous bimodal structural magnesium matrix composites with enhanced mechanical properties[J].Scientific Reports, 2016, 6:38824.
    [37]
    ZHANG Z, CHEN D L.Contribution of Orowan strengthening effect in particulate-reinforced metal matrix nanocomposites[J].Materials Science and Engineering:A, 2008, 483/484:148-152.
    [38]
    YANG M, WENG L, ZHU H X, et al.Simultaneously enhancing the strength, ductility and conductivity of copper matrix composites with graphene nanoribbons[J].Carbon, 2017, 118:250-260.
    [39]
    YANG M, WENG L, ZHU H X, et al.Leaf-like carbon nanotube-graphene nanoribbon hybrid reinforcements for enhanced load transfer in copper matrix composites[J].Scripta Materialia, 2017, 138:17-21.
    [40]
    LI C G, XIE Y H, ZHANG M W, et al.Enhanced strength and toughness of bulk ultrafine grained Cu by nacre-inspired lamellar structure[J].Journal of Alloys and Compounds, 2020, 826:154234.
    [41]
    MENG L L, WANG X J, NING J L, et al.Beyond the dimensional limitation in bio-inspired composite:Insertion of carbon nanotubes induced laminated Cu composite and the simultaneously enhanced strength and toughness[J].Carbon, 2018, 130:222-232.
    [42]
    ZHANG B, ZHANG F M, SABA F, et al.Graphene-TiC hybrid reinforced titanium matrix composites with 3D network architecture:Fabrication, microstructure and mechanical properties[J].Journal of Alloys and Compounds, 2021, 859:157777.
    [43]
    ZHANG Z X, QU J Y, FENG Y Y, et al.Assembly of graphene-aligned polymer composites for thermal conductive applications[J].Composites Communications, 2018, 9:33-41.
    [44]
    WANG C Y, SU Y S, OUYANG Q B, et al.Enhanced mechanical behavior and fabrication of graphite flakes covered by aligned graphene nanoplatelets reinforced 2A12 aluminum composites[J].Vacuum, 2021, 188:110150.
    [45]
    XIONG D B, CAO M, GUO Q, et al.Graphene-and-copper artificial nacre fabricated by a preform impregnation process:Bioinspired strategy for strengthening-toughening of metal matrix composite[J].ACS Nano, 2015, 9(7):6934-6943.
    [46]
    CHEN Y K, ZHANG X, LIU E Z, et al.Fabrication of three-dimensional graphene/Cu composite by in situ CVD and its strengthening mechanism[J].Journal of Alloys and Compounds, 2016, 688:69-76.
    [47]
    ZHANG X, SHI C S, LIU E Z, et al.In-situ space-confined synthesis of well-dispersed three-dimensional graphene/carbon nanotube hybrid reinforced copper nanocomposites with balanced strength and ductility[J].Composites Part A:Applied Science and Manufacturing, 2017, 103:178-187.
    [48]
    CHU K, WANG F, WANG X H, et al.Anisotropic mechanical properties of graphene/copper composites with aligned graphene[J].Materials Science and Engineering:A, 2018, 713:269-277.
    [49]
    WU Y, ZHANG H M, CAI H N, et al.Effects of hot-rolling reduction on microstructure and mechanical properties of GNPs/Ti composites[J].Rare Metal Materials and Engineering, 2018, 47(8):2312-2317.
    [50]
    WANG X L, WANG X, LIU M, et al.Anisotropic thermal expansion coefficient of multilayer graphene reinforced copper matrix composites[J].Journal of Alloys and Compounds, 2018, 755:114-122.
    [51]
    NAZEER\} F, MA Z, XIE Y, et al. A novel fabrication method of copper-reduced graphene oxide composites with highly aligned reduced graphene oxide and highly anisotropic thermal conductivity[J]. RSC Advances, 2019, 9(31):17967-17974. Č
    [52]
    CAO M, XIONG D B, YANG L, et al.Ultrahigh electrical conductivity of graphene embedded in metals[J].Advanced Functional Materials, 2019, 29(17):1806792.
    [53]
    CHU K, WANG X H, WANG F, et al.Largely enhanced thermal conductivity of graphene/copper composites with highly aligned graphene network[J].Carbon, 2018, 127:102-112.
    [54]
    NAZEER F, MA Z, GAO L H, et al.Thermal and mechanical properties of copper-graphite and copper-reduced graphene oxide composites[J].Composites Part B:Engineering, 2019, 163:77-85.
    [55]
    CHEN L, KUMAR S.Thermal transport in graphene supported on copper[J].Journal of Applied Physics, 2012, 112(4):043502.
    [56]
    XU Y, CHEN X B, GU B L, et al.Intrinsic anisotropy of thermal conductance in graphene nanoribbons[J].Applied Physics Letters, 2009, 95(23):233116.
    [57]
    LI X F, TAN C L, JIANG J T, et al.New construction of electron thermal conductive route for high-efficient heat dissipation of graphene/Cu composite[J].Carbon, 2021, 177:107-114.
    [58]
    YANG K M, MA Y C, ZHANG Z Y, et al.Anisotropic thermal conductivity and associated heat transport mechanism in roll-to-roll graphene reinforced copper matrix composites[J].Acta Materialia, 2020, 197:342-354.
    [59]
    LEE E, SON I, LEE J H.Starfish surface-inspired graphene-copper metaparticles for ultrahigh vertical thermal conductivity of carbon fiber composite[J].Composites Science and Technology, 2020, 199:108385.
    [60]
    QIAN S Y, XU Z H, XIE H N, et al.Effect of rare metal element interfacial modulation in graphene/Cu composite with high strength, high ductility and good electrical conductivity[J].Applied Surface Science, 2020, 533:147489.
    [61]
    ZHAO C, WANG J.Fabrication and tensile properties of graphene/copper composites prepared by electroless plating for structrual applications[J].Physica Status Solidi (A), 2014, 211(12):2878-2885.
    [62]
    SABOORI A, MOHEIMANI S, PAVESE M, et al.New nanocomposite materials with improved mechanical strength and tailored coefficient of thermal expansion for electro-packaging applications[J].Metals, 2017, 7(12):536.
    [63]
    张斌, 陈体军, 王凌云, 等.石墨烯纳米片超声分散的研究[J].功能材料, 2019, 50(8):8133-8139.

    ZHANG B, CHEN T J, WANG L Y, et al.Study on ultrasonic dispersion of graphene nanoplatelets[J].Journal of Functional Materials, 2019, 50(8):8133-8139.
    [64]
    NAZARI B, RANJBAR Z, HASHJIN R R, et al.Dispersing graphene in aqueous media:Investigating the effect of different surfactants[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2019, 582:123870.
    [65]
    DONG L L, FU Y Q, LIU Y, et al.Interface engineering of graphene/copper matrix composites decorated with tungsten carbide for enhanced physico-mechanical properties[J].Carbon, 2021, 173:41-53.
    [66]
    CHU K, WANG F, LI Y B, et al.Interface structure and strengthening behavior of graphene/CuCr composites[J].Carbon, 2018, 133:127-139.
    [67]
    LUO H B, SUI Y W, QI J Q, et al.Copper matrix composites enhanced by silver/reduced graphene oxide hybrids[J].Materials Letters, 2017, 196:354-357.
    [68]
    刘朋, 朱恩福, 闫翠霞, 等.镍含量对铜基石墨烯复合材料力电性能的影响[J].稀有金属, 2018, 42(7):735-742.

    LIU P, ZHU E F, YAN C X, et al.Strength and electrical properties of graphene reinforced copper matrix composites with different nickel contents[J].Chinese Journal of Rare Metals, 2018, 42(7):735-742.
    [69]
    CHU K, WANG J, LIU Y P, et al.Graphene defect engineering for optimizing the interface and mechanical properties of graphene/copper composites[J].Carbon, 2018, 140:112-123.
    [70]
    JIANG R R, ZHOU X F, FANG Q L, et al.Copper-graphene bulk composites with homogeneous graphene dispersion and enhanced mechanical properties[J].Materials Science and Engineering:A, 2016, 654:124-130.
    [71]
    PONRAJ N V, AZHAGURAJAN A, VETTIVEL S C, et al.Graphene nanosheet as reinforcement agent in copper matrix composite by using powder metallurgy method[J].Surfaces and Interfaces, 2017, 6:190-196.
    • Related Articles

Catalog

    Get Citation
    PDF
    XML
    Article views (13) PDF downloads (3) Cited by()
    Turn off MathJax
    Article Contents
    Abstract
    References

    Materials and Mechanical Engineering

    Address：99 Handan Road, ShanghaiPost Code: 200437

    Tel：021-65556775-368Email:mem@mat-test.com

    沪ICP备17055736号-5

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return