Effect of Modified AlN/BN Thermal Conductive Fillers on Properties of Glass Fiber Reinforced Styrene-Butadiene Resin Composites

MA Fengling; XU Qiaoyun; JIN Shilei

doi:10.11973/jxgccl202302013

Materials and Mechanical Engineering > 2023 > 47(2): 73-78. > DOI: 10.11973/jxgccl202302013

MA Fengling, XU Qiaoyun, JIN Shilei. Effect of Modified AlN/BN Thermal Conductive Fillers on Properties of Glass Fiber Reinforced Styrene-Butadiene Resin Composites[J]. Materials and Mechanical Engineering, 2023, 47(2): 73-78. DOI: 10.11973/jxgccl202302013

Citation:

PDF (2126 KB)

Effect of Modified AlN/BN Thermal Conductive Fillers on Properties of Glass Fiber Reinforced Styrene-Butadiene Resin Composites

1. Shanghai Key Laboratory of Engineering Materials Application and Evaluation, Shanghai Research Institute of Materials Co., Ltd., Shanghai 200437, China;
2. Shanghai Institute of Satellite Engineerring, Shanghai 200240, China

More Information

Received Date: August 25, 2021
Revised Date: October 12, 2022

Graphical Abstract

Abstract

Abstract

AlN and BN were modified with silane coupling agent KH570 under anhydrous conditions, and then were used as thermal conductive fillers added into glass fiber reinforced styrene-butadiene resin composites. The effect of different thermal conductive fillers on the water absorption, thermal conductivity, dielectric properties and mechanical properties of the composite was studied. The results show that filling the two thermal conductive fillers could improve the water absorption of the composite; comparing with the unmodified filler, the filling of the modified filler had a small increase in water absorption of the composite. With the increase of modified AlN content, the dielectric constant and dielectric loss of the composite increased significantly, indicating the dielectric properties decreased, and the flexural strength increased first and then decreased. With the increase of modified BN content, the dielectric constant of the composite increased, the dielectric loss decreased, and the flexural strength increased. The two modified thermal conductive fillers could improve the thermal conductivity of the composite. Compared with single component filling, modified AlN and modified BN hybrid filling had a stronger effect on improving the thermal conductivity of the composite.
- aluminum nitride,
- boron nitride,
- surface treatment,
- styrene-butadiene resin matrix composite,
- thermal conductivity,
- dielectric property

FullText(HTML)

References (18)

References

[1]	赵敬棋, 孟凡成, 申景博, 等.导热高分子复合材料的研究进展[J].化学工业与工程, 2020, 37(3):67-73. ZHAO J Q, MENG F C, SHEN J B, et al.Research progress of thermal conductive polymer composites[J].Chemical Industry and Engineering, 2020, 37(3):67-73.
[2]	闫智伟, 张文君.导热型覆铜板研究进展[J].覆铜板资讯, 2014(2):27-32. YAN Z W, ZHANG W J.Research progress of thermal conductive copper clad laminate[J]. Copper Clad Laminate lnformation, 2014(2):27-32.
[3]	刘少刚, 王李波, 王晓龙, 等.高导热网络聚合物基复合材料的研究进展[J].中国塑料, 2019, 33(8):127-135. LIU S G, WANG L B, WANG X L, et al.Research progress in polymer matrix composites with highly thermally conductive network[J].China Plastics, 2019, 33(8):127-135.
[4]	张金成, 冯一峻, 肖文军, 等.填充型聚合物基导热复合材料的研究进展[J].杭州师范大学学报(自然科学版), 2019, 18(5):476-482. ZHANG J C, FENG Y J, XIAO W J, et al.On filled polymer-based thermal conductive composites[J].Journal of Hangzhou Normal University (Natural Science Edition), 2019, 18(5):476-482.
[5]	何亭融, 曲绍宁, 尹训茜.电子封装用环氧树脂/氮化硼导热复合材料的研究进展[J].绝缘材料, 2020, 53(7):12-17. HE T R, QU S N, YIN X Q.Research progress of epoxy resin/boron nitride thermal conductive composites for electronic packaging[J].Insulating Materials, 2020, 53(7):12-17.
[6]	GUERRA V, WAN C Y, MCNALLY T.Thermal conductivity of 2D nano-structured boron nitride (BN) and its composites with polymers[J].Progress in Materials Science, 2019, 100:170-186.
[7]	林正得, 颜庆伟, 代文, 等.六方氮化硼导热复合材料研究进展[J].集成技术, 2019, 8(1):24-37. LIN C T, YAN Q W, DAI W, et al.Research progress on hexagonal boron nitride-based thermal conductive composites[J].Journal of Integration Technology, 2019, 8(1):24-37.
[8]	KOCJAN A.The hydrolysis of AlN powder:A powerful tool in advanced materials engineering[J].The Chemical Record, 2018, 18(7/8):1232-1246.
[9]	段家真, 金石磊, 马峰岭, 等.助剂对丁苯橡胶基高频覆铜层压板性能的影响[J].理化检验(物理分册), 2021, 57(6):38-41. DUAN J Z, JIN S L, MA F L, et al.Effect of additives on properties of styrene-butadien rubber based high frequency copper clad laminate[J].Physical Testing and Chemical Analysis (Part A:Physical Testing), 2021, 57(6):38-41.
[10]	袁镇.AlN@Al₂O₃/EP导热复合材料的制备及性能研究[D].哈尔滨:哈尔滨理工大学, 2020. YUAN Z.Preparation and properties of AlN@Al₂O₃/EP thermal conductive composites[D].Harbin:Harbin University of Science and Technology, 2020.
[11]	王宝玉, 张苏明, 兰玉顺, 等.KH-570表面改性超细SiO₂的研究[J].北京化工大学学报(自然科学版), 2010, 37(5):30-34. WANG B Y, ZHANG S M, LAN Y S, et al.Experimental studies of the surface modification of silica by the silane coupling agent γ-methacryloxypropyltrimethoxysilane(KH-570)[J].Journal of Beijing University of Chemical Technology (Natural Science Edition), 2010, 37(5):30-34.
[12]	张维维, 陆晨, 应国兵, 等.AlN表面处理及级配填充对覆铜板绝缘层性能的影响规律与机制研究[J].无机材料学报, 2021, 36(8):847-855. ZHANG W W, LU C, YING G B, et al.Effect and mechanism of the surface treatment and gradation filling of AlN on the performance of insulation layer of copper clad laminate[J].Journal of Inorganic Materials, 2021, 36(8):847-855.
[13]	张惠娟, 王涛, 孟维晓, 等.氮化硼填充导热绝缘塑料的研究及应用[J]. 塑料工业, 2019, 47(6):22-26. ZHANG H J, WANG T, MENG W X, et al. Research and application of boron nitride filled thermal conductive and electrical insulating plastics[J]. China Plastics Industry, 2019, 47(6):22-26.
[14]	JIN H Y, WANG W, GAO J Q, et al. Study of machinable AlN/BN ceramic composites. Materials Letters, 2006, 60(2):190-193.
[15]	侯军.氮化硼环氧树脂导热复合材料的制备与性能研究[D].天津:河北工业大学, 2015. HOU J. Preparation and properties of thermally conductive boron nitride/epoxy composites[D]. Tianjin:Hebei University of Technology, 2015.
[16]	迟志峰.AlN陶瓷填充PTFE基板制备及性能研究[D].成都:电子科技大学, 2019. CHI Z F.The researches of preparation and properties of AlN ceramic filled PTFE substrate[D].Chengdu:University of Electronic Science and Technology of China, 2019.
[17]	徐昉, 薛杰, 李响, 等.SiC-BN填料杂化柔性电绝缘高导热材料[J].高分子材料科学与工程, 2018, 34(9):156-159. XU F, XUE J, LI X, et al.SiC-BN hybrid highly elastic and electrical insulated thermal conductive material[J].Polymer Materials Science & Engineering, 2018, 34(9):156-159.
[18]	马馨雨.BN、AlN掺杂的高导热PI复合薄膜的制备与性能研究[D].哈尔滨:哈尔滨理工大学, 2019. MA X Y.Preparation and properties of BN and AlN doped pi composite films with high thermal conductivity[D].Harbin:Harbin University of Science and Technology, 2019.

Cited By

Get Citation

PDF

XML

Article views (4) PDF downloads (2)

Turn off MathJax

Article Contents

Abstract

References

Effect of Modified AlN/BN Thermal Conductive Fillers on Properties of Glass Fiber Reinforced Styrene-Butadiene Resin Composites

Abstract

References

Catalog

Export File

Citation

Format

Content