Effect of Al<sub><i>x</sub></i>CoCrFeNi High-Entropy Alloy Binder on Microstructure and High-Temperature Oxidation Resistance of Ti(C,N)-Based Cermets

FANG Ding; YU Ze; GOU Shaoxuan

doi:10.11973/jxgccl202311009

Materials and Mechanical Engineering > 2023 > 47(11): 51-56. > DOI: 10.11973/jxgccl202311009

FANG Ding, YU Ze, GOU Shaoxuan. Effect of Al_xCoCrFeNi High-Entropy Alloy Binder on Microstructure and High-Temperature Oxidation Resistance of Ti(C,N)-Based Cermets[J]. Materials and Mechanical Engineering, 2023, 47(11): 51-56. DOI: 10.11973/jxgccl202311009

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Effect of Al_xCoCrFeNi High-Entropy Alloy Binder on Microstructure and High-Temperature Oxidation Resistance of Ti(C,N)-Based Cermets

AVIC Chengdu Aircraft Industrial (Group) Co., Ltd., Chengdu 610092, China

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Received Date: May 25, 2022
Revised Date: June 08, 2023

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Abstract

Ti(C, N)-based cermets were prepared by low-pressure sintering with Al_xCoCrFeNi high-entropy alloy (x=0, 0.5, 1, molar ratio) as the binder, and the effects of Al_xCoCrFeNi high-entropy alloy binder on the microstructure and high-temperature oxidation resistance of cermets were investigated. The results show that the prepared cermets were mainly composed of Ti(C, N) phase with face-centered cubic (FCC) structure and high-entropy alloy binder phase with FCC structure, and the transformation from body-centered cubic (BCC) structure phase to FCC structure phase occurred in Al_0.5CoCrFeNi and AlCoCrFeNi high-entropy alloys during high-temperature sintering. The cermets all had a typical core-ring structure, and there were more pores in the cermets prepared with AlCoCrFeNi high-entropy alloy binder. After oxidizing at 1 000℃ for 6 h, the mass gains per unit area of cermets prepared with CoCrFeNi, Al_0.5CoCrFeNi, and AlCoCrFeNi high-entropy alloy binders were 3.58, 2.95, 2.81 mg·cm^-2, respectively, and the cermets prepared with AlCoCrFeNi high-entropy alloy binder had the best high-temperature oxidation resistance.
- Ti(C,N)-based cermet,
- Al_xCoCrFeNi high-entropy alloy,
- microstructure,
- high-temperature oxidation resistance

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Effect of AlxCoCrFeNi High-Entropy Alloy Binder on Microstructure and High-Temperature Oxidation Resistance of Ti(C,N)-Based Cermets

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Effect of Al_xCoCrFeNi High-Entropy Alloy Binder on Microstructure and High-Temperature Oxidation Resistance of Ti(C,N)-Based Cermets