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WEI Xiang-fei, ZHANG Ping-ze, WEI Dong-bo, SHA Li-li, ZHOU Peng, ZHANG Yang. High-Temperature Oxidation Behavior of Double Glow Plasma Cr-W Alloying Layer on γ-TiAl Alloy Surface[J]. Materials and Mechanical Engineering, 2014, 38(5): 12-16.
Citation: WEI Xiang-fei, ZHANG Ping-ze, WEI Dong-bo, SHA Li-li, ZHOU Peng, ZHANG Yang. High-Temperature Oxidation Behavior of Double Glow Plasma Cr-W Alloying Layer on γ-TiAl Alloy Surface[J]. Materials and Mechanical Engineering, 2014, 38(5): 12-16.

High-Temperature Oxidation Behavior of Double Glow Plasma Cr-W Alloying Layer on γ-TiAl Alloy Surface

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  • Received Date: February 15, 2014
  • Cr-W alloying layer was prepared on TiAl alloy by using the double glow plasma surface alloying technology(DGP), and the high temperature oxidation behavior of the alloying layer was tested by SEM, EDX, XRD and high temperature oxidation experiment. The results show that the surface morphology of the Cr-W alloying layer is smooth and the microstructure is uniform. The alloying layer closely connects with the matrix, without holes, cracks and other defects on the joint. The Cr-W alloying layer at high temperature can form a protective film to reduce the rate of oxidation effectively. The anti-oxidantion capacity of the alloying layer is significantly improved, and the oxidation weight gain is lower than that of the matrix. With the increase of the oxidation temperature, the oxidation weight gain of the alloying layer increases significantly and the oxidation mechanism is unchanged. In the oxidation process, the internal diffusion of Cr and W is found, together with the external diffusion of Ti and Al.
  • [1]
    YE H Q. Recent developments in Ti3Al and TiAl intermetallics research in China[J].Materials Science and Engineering:A,1999,263(2):289-295.
    [2]
    黄劲松, 刘咏, 贺跃辉, 等.Ti-Al-Nb-W-B合金不同工艺处理状态的组织演变及钨的作用[J].金属热处理,2006(7):13-17.
    [3]
    郑婷,骆心怡,孙晓宾,等.钛合金表面抗氧化技术的研究进展[J].机械工程材料,2010,34(4):11-13.
    [4]
    ZHANG W J, FRANCESCONI L, EVANGELISTA E. A novel heat treatment to develop very fine lamellar structure in cast gamma-base TiAl alloys[J].Materials Letters,1996,27(4/5):135-138.
    [5]
    LI X Y, TANIGUCHI S. Oxidation behavior of a γ-TiAl-based alloy implanted by silicon and/or carbon[J].Materials Science and Engineering:A,2005,398(1/2):268-274.
    [6]
    MUKHERJEE S, MAITZ M F, PHAM M T, et al. Development and biocompatibility of hard Ti-based coatings using plasma immersion ion implantation-assisted deposition[J].Surface and Coatings Technology, 2005, 196(1/3): 312-316.
    [7]
    LI X Y, TANIGUCHI S, ZHU Y C, et al. Oxidation beha-vior of TiAl protected by Si+Nb combined ion implantation[J].Intermetallics,2001,9(5):443-449.
    [8]
    GRAY S, JACOBS M H, PONTON C B, et al. A method of heat-treatment of near γ-TiAl to enhance oxidation resistance by the formation of a Ti5Si3 layer[J].Materials Science and Engineering: A,2004,384(1/2):77-82.
    [9]
    周海,陈飞,姚斌,等.TiAl 合金表面等离子喷涂双层涂层组织与性能的研究[J].机械工程材料,2004,28(7):37-39.
    [10]
    王东生, 田宗军, 陈志勇, 等.TiAl合金表面抗高温氧化涂层研究[J].中国腐蚀与防护学报,2009(1):1-8.
    [11]
    王福会, 唐兆麟.TiAl金属间化合物的高温氧化与防护研究进展[J].材料研究学报,1998(4):337-344.
    [12]
    TEDMON JR C S. The high-temperature oxidation of ductile Cr Ru alloys[J].Journal of the Less Common Metals,1966,10(5):301-311.
    [13]
    GULBRANSEN E A. Infra-red heating source and associated apparatus for the study of contaminants in inert gases[J].Thermochimica Acta,1979,29(2):295-299.
    [14]
    高原, 徐晋勇, 高清, 等.双层辉光离子渗金属技术特点分析[J].热加工工艺,2006(3):56-59.
    [15]
    CASTALDI L, KURAPOV D, REITER A, et al. High temperature phase changes and oxidation behavior of Cr-Si-N coatings[J].Surface and Coatings Technology,2007,202(4/7):781-785.
    [16]
    WEI D B, ZHANG P Z, YAO Z J, et al. Oxidation of double-glow plasma chromising coating on TC4 titanium alloys[J].Corrosion Science,2013,66:43-50.
    [17]
    LEYENS C, VAN LIERE J W, PETERS M, et al. Magnetron-sputtered Ti-Cr-Al coatings for oxidation protection of titanium alloys[J].Surface and Coatings Technology,1998,108/109:30-35.
    [18]
    童长青, 成来飞, 张立同, 等.C/SiC-W复合材料的制备与表征[J].航空材料学报,2006(3):152-156.
    [19]
    彭其春, 李光强, 朱诚意.稀土元素对Fe-Cr-Al系合金抗氧化性的影响[J].稀土,2003(5):13-17.
    [20]
    魏东博, 张平则, 姚正军, 等. TC4合金双辉等离子渗Cr高温氧化行为[J].材料热处理学报,2011(10):146-150.

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