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DONG Wei, LU Jin-shan, LI Yao-hui. Effects of Melt Forming Rate on Microstructure of Glass-Ceramics[J]. Materials and Mechanical Engineering, 2011, 35(12): 22-25.
Citation: DONG Wei, LU Jin-shan, LI Yao-hui. Effects of Melt Forming Rate on Microstructure of Glass-Ceramics[J]. Materials and Mechanical Engineering, 2011, 35(12): 22-25.

Effects of Melt Forming Rate on Microstructure of Glass-Ceramics

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  • Received Date: July 13, 2011
  • Lithium aluminosilicate glass with different melt forming rates were prepared by the melting method. The effect of forming rate on the microstructure of heat-treated glass-ceramics was analyzed using XRD, DTA, IR and SEM techniques. The results show that the replacement of some Al3+ for Si4+ occurred in the interior of glass with low forming rate in the process of slow cooling(1 cm·s-1), which led to the primary nuclei precipitated. The glass interior converted into a white β-spodumene structure after heat treatment. Meanwhile, because of rapid cooling of the glass surface, the nucleation did not occur obviously. A transparent and colorless β-quartz solid solution was formed after heat treatment. High melt forming rate(6 cm·s-1) led to rapid cooling in the interior of glass,too. A single β-quartz solid solution was formed on surface and in interior after heat treament.
  • [1]
    殷海荣,吕承珍,李阳,等.零膨胀锂铝硅透明微晶玻璃的研究与应用现状[J]. 硅酸盐通报,2008,27(3):537-542.
    [2]
    MATTARELLI M, MONTAGNA M, VERROCCHIO P.Ultratransparent glass ceramics:the structure factor and the quenching of the rayleigh scattering [J]. Applied Physics Letters,2007,91(6):0619111-0619113.
    [3]
    赵彦钊,殷海荣.玻璃工艺学[M]. 北京:化学工业出版社,2006.
    [4]
    GUPTA P K, BARANTA G, DENRY I L.DTA peak shift studies of primary crystallization in glasses[J]. Journal of Non-Crystalline Solids,2003,317:254-269.
    [5]
    ARVIND A, RAKESH K, DEO M N,et al.Preparation, structural and thermo-mechanical properties of lithium aluminum silicate glass-ceramics[J]. Ceramics International,2009,35:1661-1666.
    [6]
    HOU Z X, ZHANG Y M, ZHANG H S,et al.Study on crystallization and microstructure of Li2O-Al2O3-SiO2 glass ceramics [J]. Journal of University of Science and Technology Beijing,2006,13(6):564-570.
    [7]
    隋普辉,陆雷,武相萍,等.晶化温度对Li2O-ZnO-Al2O3-SiO2微晶玻璃物相组成和热膨胀系数的影响[J]. 机械工程材料,2009,33(5):14-17.
    [8]
    吴松全,李亚娟,王福平.Li2O-Al2O3-SiO2系微晶玻璃的制备方法和应用现状[J]. 硅酸盐通报,2005,24(1):76-81.
    [9]
    ARNAULT L, GERLAND M, RIVIERE A.Microstructural study of two LAS-type glass-ceramics and their parent glass [J]. Journal of Materials Science, 2000,35:2331-2345.
    [10]
    隋普辉,陆雷.锂锌铝硅系微晶玻璃的显微结构及性能[J]. 宇航材料工艺,2009,39(6):33-37.
    [11]
    GUEDES M, FERRO A C, FERREIRA J M F.Nucleation and crystal growth in commercial LAS composition [J]. Journal of the European Ceramic Society,2001,21:1187-1194.

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