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WU Hai-jiang, LU Jin-tang. Preparation and Corrosion Resistance of Silane Film on Hot-dip Galvanized Steel[J]. Materials and Mechanical Engineering, 2009, 33(7): 52-55.
Citation: WU Hai-jiang, LU Jin-tang. Preparation and Corrosion Resistance of Silane Film on Hot-dip Galvanized Steel[J]. Materials and Mechanical Engineering, 2009, 33(7): 52-55.
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Preparation and Corrosion Resistance of Silane Film on Hot-dip Galvanized Steel

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  • Received Date: March 13, 2009
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    • Abstract
  • A nontoxic silanized treatment process for hot-dip galvanized steel was investigated by the orthogonal experiment.The protection of silane films on galvanized steel surface was evaluated by neutral salt spray test and polarization test.The factors affecting the corrosion resistance of silane films were discussed,including concentration of silane solution,concentration of methanol,hydrolysis time,hydrolysis temperature,pH of silane solution and immersion time.The optimum technological parameters were obtained,and the mechanism was analyzed.The results show that the silane films had the optimum anti-corrosion properties under the conditions of concentration of the silane solution 7%,concentration of methanol in hydrolysis solvents 10%,hydrolysis time 6 h,hydrolysis temperature 40℃,pH of the silane solution 4 and immersion time 120 s acted as a physical barrier of galvanized steel and suppressed both cathodic and anodic reactions of corrosion simultaneously.The time of white rust occurence on galvanized coating was delayed.The silane films obtained excellent corrosion resistance under the optimum technological conditions.
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    • References (15)
  • [1]
    EICHINGER E,OSBORNE J,CLEAVE T V.Hexavalent chromium elimination: an aerospace industry progress report[J].Metal Finishing,1997,95(3):36-41.
    [2]
    MAGALHAES A A O,MARGARIT I C P,MATTOS O R.Molybdate conversion coatings on zinc surfaces[J].Journal of Electroanalytical Chemistry,2004,572(2):433-440.
    [3]
    VEERARAGHAVAN B,SLAVKOV D,PRABHU S,et al.Synthesis and characterization of a novel non-chrome electrolytic surface treatment process to protect zinc coatings[J].Surface and Coatings Technology,2003,167(1):41-51.
    [4]
    MONTEMOR M F,SIMES A M,FERREIRA M G S.Composition and behaviour of cerium films on galvanised steel[J].Progress in Organic Coatings,2001,43(4):274-281.
    [5]
    MONTEMOR M F,ROSQVIST A,FAGERHOLM H,et al.The early corrosion behaviour of hot dip galvanised steel pre-treated with bis-1,2-(triethoxysilyl)ethane[J].Progress in Organic Coatings,2004,51(3):188-194.
    [6]
    ZHU D Q,VAN O W J.Enhanced corrosion resistance of AA 2024-T3 and hot-dip galvanized steel using a mixture of bis-[triethoxysilylpropyl] tetrasulfide and bis-[trimethoxysilylpropyl] amine[J].Electrochimica Acta,2004,49(7):1113-1125.
    [7]
    TRABELSI W,DHOUIBI L,TRIKI E,et al.An electrochemical and analytical assessment on the early corrosion behaviour of galvanised steel pretreated with aminosilanes[J].Surface and Coatings Technology,2005,192(2):284-290.
    [8]
    关颖男,施大德.试验设计方法入门[M].北京:冶金工业出版社,1985:181.
    [9]
    王雪明,李爱菊,李国丽,等.金属表面KH-560硅烷膜的粘结性能研究[J].机械工程材料,2005,29(11):8-10.
    [10]
    刘倞,胡吉明,张鉴清,等.金属表面硅烷化防护处理及其研究现状[J].中国腐蚀与防护学报,2006,26(1):59-64.
    [11]
    VAN O W J,CHILD T F.Protecting metals with silane coupling agents[J].Chemtech,1998,28(2):26-35.
    [12]
    胡吉明,刘倞,张金涛,等.铝合金表面BTSE硅烷化处理研究[J].金属学报,2004,40(11):1189-1194.
    [13]
    BEARI F,BRAND M,JENKNER P,et al.Organofunctional alkoxysilanes in dilute aqueous solution: new accounts on the dynamic structural mutability[J].Journal of Organometallic Chemistry,2001,625:208-216.
    [14]
    SUBRAMANIAN V,VAN O W J.Silane based metal pretreatments as alternatives to chromating[J].Surface Engineering,1999,15(2):168-172.
    [15]
    ABEL M L,WATTS J F,DIGBY R P.The adsorption of alkoxysilanes on oxidized aluminium substrates[J].International Journal of Adhesion and Adhesives,1998,18(3):179-192.
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