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MA Na, ZHENG Xing-hua, TANG De-ping. Microstructure, Sintering and Dielectric Properties of (1-x)Sr1.85Ca0.15NaNb5O15-xBiFeO3 Ceramics[J]. Materials and Mechanical Engineering, 2012, 36(1): 68-71.
Citation: MA Na, ZHENG Xing-hua, TANG De-ping. Microstructure, Sintering and Dielectric Properties of (1-x)Sr1.85Ca0.15NaNb5O15-xBiFeO3 Ceramics[J]. Materials and Mechanical Engineering, 2012, 36(1): 68-71.
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Microstructure, Sintering and Dielectric Properties of (1-x)Sr1.85Ca0.15NaNb5O15-xBiFeO3 Ceramics

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  • Received Date: June 30, 2011
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    • Abstract
  • (1-x)Sr1.85Ca0.15NaNb5O15-xBiFeO3 (SCNN-BFO) ceramics with tungsten brone structure were prepared by solid phase reaction method. The effects of BFO contents on microstructure, sintering and dielectric properties of the ceramics were studied. The results show that sintering temperature to make the ceramics owning maximum densy decreased from 1 350 ℃ to 1 250 ℃ when was more than or equal to 0.1, and sintering cracking was restrained. Sr2(FeNb)O6 and Bi1.34Fe0.66Nb1.34O6.35 phases appeared when x=0.2, the both content increased with BFO contents, and Bi1.34Fe0.66Nb1.34O6.35 became the major phase when x=0.6. Dielectric constant and dielectric loss were low when x＜0.1, low frequency dielectric constant increased rapidly with the increase of BFO content, and the dielectric loss appeared peak value and then decreased.
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    • References (19)
  • [1]
    UMALAMTHAM K, NARAYANA S. Effect of rare-earth ions on the properties of modified (SrBa)Nb2O6 ceramics [J].J Mater Lett, 1987, 6: 565-567.
    [2]
    赵焕绥, 任天令, 张沛霖, 等. Sr1.95Ca0.05NaNb5O15晶体的介电热电和热学性质[J].山东大学学报: 自然科学版, 1993, 28(3): 311-315.
    [3]
    NEURGAONKAR R R, HALL W F, OLIVER J R. Growth and ferroelectric properties of tungsten bronze Sr2-xCaxNaNb5O15 single crystals [J].Ferroelectrics, 1988, 23: 1459-1467.
    [4]
    NEURGAONKAR R R, OLIVER J R, COPY W K, et al. Piezoelectricity in tungsten bronze crystals [J].Ferroelectrics, 1994, 160: 265-276.
    [5]
    韩兆忠, 孙大亮, 杨兆荷, 等. 新型钨青铜结构晶体SCNN [J].硅酸盐学报, 1993, 21(4): 376-379.
    [6]
    JAMIESON P B, ABRAHAMS S C, BERNSTEIN J L. Ferroelectric tungsten bronze-type crystal structures II: barium sodium niobate Ba(4+x)Na(2-2x)Nb10O30 [J].J Chem Phys, 1969, 50(10): 4352-4363.
    [7]
    FRANCOMBE M H. The relation between structure and ferroelectricity in lead barium and barium strontium niobates[J].Acta Crystallogr, 1960, 13: 131-140.
    [8]
    KIMURA T, MIYAMOTO S, YAMAGUCHI T. Microstructure development and dielectric properties of potassium strontium niobate ceramics [J].J Am Ceram Soc, 1990, 73(1): 127-130.
    [9]
    MATSUO K, XIE R J, AKIMUNE Y, et al. Preperation of lead-free Sr2-xCaxNaNb5O15(x=0.1)-based piezoceramics with tungsten bronze structure [J].J Ceram Soc Jpn, 2002, 110(5): 491-494.
    [10]
    XIE R J, AKIMUNE Y, WANG R P, et al. Spark plasma sintering of tungsten bronze Sr2-xCaxNaNb5O15(x=0.1) piezoelectric ceramics II: electrical properties [J].J Am Ceram Soc, 2002, 85(11): 2731-2737.
    [11]
    XIE R J, AKIMUNE Y, MATSUO K, et al. Dielectric and ferroelectric properties of tetragonal tungsten bronze Sr2-xCaxNaNb5O15(x=0.05-0.35)ceramics [J].Appl Phys Lett, 2002, 80: 835-837.
    [12]
    XIE R J, AKIMUNE Y. Lead-free piezoelectric ceramics in the Sr2-xCaxNaNb5O15(x=0.05-0.35)system [J].J Mater Chem, 2002, 12: 3156-3161.
    [13]
    XIE R J, AKIMUNE Y, WANG R P, et al. Spark plasma sintering of tungsten bronze Sr2-xCaxNaNb5O15(x=0.1) piezoelectric ceramics I: processing and microstructure [J]. J Am Ceram Soc, 2002, 85(11): 2725-2730.
    [14]
    FILIPPETTI A, HILL N A. First principles study of structural, electronic and magnetic interplay in ferroelectromagnetic yttrium manganite [J].J Magn Magn Mater, 2001, 236: 176-186.
    [15]
    KUBEL F, SCHMID H. Structure of ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3 [J]. Acta Cryst B, 1990, 46: 698-702.
    [16]
    YUAN G L, WANG Y P, LIU Z G, et al. Preparation and multi-properties of insulated single-phase BiFeO3 ceramics [J]. Solid State Comm, 2006, 138: 76-81.
    [17]
    王越, 张依才, 胡振江, 等. SCNN无铅压电陶瓷的制备和特性研究[J].北京工业大学学报, 2009, 35(1): 125-129.
    [18]
    崔玉, 杜慧玲, 史翔, 等, 含Sr铋基焦绿石材料的介电弛豫性能[J].硅酸盐学报, 2010, 38(6): 1007-1012.
    [19]
    方俊鑫, 殷之文.电介质物理学[M].北京: 科学出版社, 2000.
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